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通过化学路线合成的用于稳定高效可充电锂离子电池的硫化铜钴锡(CuCoSnS)阳极。

Copper cobalt tin sulphide (CuCoSnS) anodes synthesised using a chemical route for stable and efficient rechargeable lithium-ion batteries.

作者信息

Inamdar Akbar I, Hou Bo, Chavan Harish S, Salunke Amol S, Han Jonghoon, Shin Giho, Park Sunjung, Yeon Seungun, Shrestha Nabeen K, Im Hyunsik, Kim Hyungsang

机构信息

Division of Physics and Semiconductor Science, Dongguk University, Seoul 04620, Republic of Korea.

Department of Engineering Science, University of Oxford, Parks Road, OX1 3PJ, UK.

出版信息

Dalton Trans. 2022 Oct 4;51(38):14535-14544. doi: 10.1039/d2dt01966c.

Abstract

In everyday life, superior lithium-ion batteries (LIBs), with fast charging ability, have become valuable assets. The LIB performance of an anode composite copper cobalt tin sulphide (CuCoSnS; CCTS) electrode, which was fabricated using a simple and easy hydrothermal method, was investigated. The electrochemical charge storage performance of the CCTS anode demonstrated sustainability, high-rate capability and efficiency. The CCTS anode exhibited a first discharge capacity of 914.5 mA h g and an average specific capacity of 198.7 mA h g in consecutive cycles at a current density of 0.1 A g. It had a capacity retention of ∼62.0% and a coulombic efficiency of more than 83% after over 100 cycles, demonstrating its excellent cycling performance and reversibility. It can be an alternative anode to other established electrode materials for real battery applications.

摘要

在日常生活中,具有快速充电能力的优质锂离子电池(LIBs)已成为宝贵资产。研究了采用简单易行的水热法制备的阳极复合铜钴锡硫化物(CuCoSnS;CCTS)电极的LIB性能。CCTS阳极的电化学电荷存储性能表现出可持续性、高倍率性能和效率。在0.1 A g的电流密度下,CCTS阳极在连续循环中首次放电容量为914.5 mA h g,平均比容量为198.7 mA h g。经过100多次循环后,其容量保持率约为62.0%,库仑效率超过83%,证明了其优异的循环性能和可逆性。在实际电池应用中,它可以作为其他既定电极材料的替代阳极。

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