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使用玄武岩纤维作为增强层的可降解仿生高敏感应变传感器,具有高强度机械性能。

Degradable Bioinspired Hypersensitive Strain Sensor with High Mechanical Strength Using a Basalt Fiber as a Reinforced Layer.

机构信息

Key Laboratory of Bionic Engineering, Ministry of Education, Jilin University, Changchun 130022, China.

The State Key Laboratory of High Performance and Complex Manufacturing, College of Mechanical and Electrical Engineering, Central South University, Changsha 410012, China.

出版信息

ACS Appl Mater Interfaces. 2022 Sep 21;14(37):42723-42733. doi: 10.1021/acsami.2c12479. Epub 2022 Sep 8.

Abstract

Flexible strain sensors have received extensive attention due to their broad application prospects. However, a majority of present flexible strain sensors may fail to maintain normal sensing performances upon external loads because of their low strength and thus their performances are affected drastically with increasing loads, which severely restricts large-area popularization and application. Scorpions with hypersensitive vibration slit sensilla are coincident with a similar predicament. Herein, it is revealed that scorpions intelligently use risky slits to detect subtle vibrations, and meanwhile, the distinct layered composites of the main body of this organ prevent catastrophic failure of the sensory structure. Furthermore, the extensive use of flexible sensors will generate a mass of electronic waste just as obsoleting silicon-based devices. Considering mechanical properties and environmental issues, a flexible strain sensor based on an elastomer (Ecoflex)-wrapped fabric with the woven structure was designed and fabricated. Note that introducing a "green" basalt fiber (BF) into a degradable elastomer can effectively avoid environmental issues and significantly enhance the mechanical properties of the sensor. As a result, it shows excellent sensitivity (gauge factor (GF) ∼138.10) and high durability (∼40,000 cycles). Moreover, the reduced graphene oxide (RGO)/BF/Ecoflex flexible strain sensor possesses superior mechanical properties (tensile strength ∼20 MPa) and good flexibility. More significantly, the sensor can maintain normal performances under large external tensions, impact loads, and even underwater environments, providing novel design principles for environmentally friendly flexible sensors under extremely harsh environments.

摘要

柔性应变传感器由于其广阔的应用前景而受到广泛关注。然而,目前大多数的柔性应变传感器由于强度较低,在外力作用下无法保持正常的传感性能,因此随着负载的增加,其性能会急剧下降,这严重限制了其在大面积的推广和应用。具有超敏感振动狭缝感受器的蝎子也面临着类似的困境。在此,研究人员揭示了蝎子巧妙地利用危险的狭缝来检测微妙的振动,同时,这个器官主体的分层复合材料防止了传感结构的灾难性失效。此外,广泛使用的柔性传感器将产生大量电子垃圾,就像淘汰硅基器件一样。考虑到机械性能和环境问题,设计并制作了一种基于弹性体(Ecoflex)包裹的具有编织结构的织物的柔性应变传感器。值得注意的是,在可降解弹性体中引入“绿色”玄武岩纤维(BF)可以有效地避免环境问题,并显著提高传感器的机械性能。结果表明,它具有优异的灵敏度(应变系数(GF)∼138.10)和高耐用性(∼40000 次循环)。此外,还原氧化石墨烯(RGO)/BF/Ecoflex 柔性应变传感器具有优异的机械性能(拉伸强度∼20 MPa)和良好的柔韧性。更重要的是,该传感器在大外部张力、冲击负载甚至水下环境下都能保持正常性能,为在极其恶劣环境下的环保型柔性传感器提供了新的设计原则。

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