Choi Sieun, Kurosu Shunji, Mashiko Yuta, Minakawa Takanobu, Maekawa Toru
Graduate School of Interdisciplinary New Science, Toyo University, 2100, Kujirai, Kawagoe, Japan.
Bio-Nano Electronics Research Centre, Toyo University, 2100, Kujirai, Kawagoe, Japan.
Sci Rep. 2022 Sep 8;12(1):15207. doi: 10.1038/s41598-022-19475-z.
A carbon nanobelt (CNB) is a loop of fused benzene rings and a C molecule is a football shaped fullerene composed of 60 carbon atoms. In this study, we synthesize uniform spherical particles composed of (6,6)CNBs and C molecules in 1,2-dichlorobenzene at room temperature via bottom-up self-assembly, setting the molar concentrations of (6,6)CNBs and C molecules at appropriate values, and find that the particles are monodisperse even in water. The present room temperature synthetic methodology may well be applied to the creation of nano/micro structures/materials using basic carbon nano units such as cycloparaphenylene (CPP, carbon nanorings) and fullerenes; e.g., C, C and CN.
碳纳米带（CNB）是由稠合苯环构成的环，而C分子是由60个碳原子组成的足球状富勒烯。在本研究中，我们通过自下而上的自组装方法，在室温下于1,2 - 二氯苯中合成了由（6,6）碳纳米带和C分子组成的均匀球形颗粒，将（6,6）碳纳米带和C分子的摩尔浓度设定为适当的值，并发现这些颗粒即使在水中也是单分散的。目前的室温合成方法很可能适用于使用基本碳纳米单元（如环对亚苯基（CPP，碳纳米环）和富勒烯）来创建纳米/微结构/材料；例如，C、C和CN。
