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镍-氧化镍纳米复合材料作为高性能锂离子电池阳极的最新进展综述

A Review on Recent Advancements of Ni-NiO Nanocomposite as an Anode for High-Performance Lithium-Ion Battery.

作者信息

Siddiqui Safina-E-Tahura, Rahman Md Arafat, Kim Jin-Hyuk, Sharif Sazzad Bin, Paul Sourav

机构信息

Department of Mechanical Engineering, Chittagong University of Engineering and Technology, Chittagong 4349, Bangladesh.

Clean Energy R&D Department, Korea Institute of Industrial Technology, 89 Yangdaegiro-gil, Ip-jang-myeon, Seobuk-gu, Cheonan-si 31056, Chungcheongnam-do, Korea.

出版信息

Nanomaterials (Basel). 2022 Aug 25;12(17):2930. doi: 10.3390/nano12172930.

Abstract

Recently, lithium-ion batteries (LIBs) have been widely employed in automobiles, mining operations, space applications, marine vessels and submarines, and defense or military applications. As an anode, commercial carbon or carbon-based materials have some critical issues such as insufficient charge capacity and power density, low working voltage, deadweight formation, short-circuiting tendency initiated from dendrite formation, device warming up, etc., which have led to a search for carbon alternatives. Transition metal oxides (TMOs) such as NiO as an anode can be used as a substitute for carbon material. However, NiO has some limitations such as low coulombic efficiency, low cycle stability, and poor ionic conductivity. These limitations can be overcome through the use of different nanostructures. This present study reviews the integration of the electrochemical performance of binder involved nanocomposite of NiO as an anode of a LIB. This review article aims to epitomize the synthesis and characterization parameters such as specific discharge/charge capacity, cycle stability, rate performance, and cycle ability of a nanocomposite anode. An overview of possible future advances in NiO nanocomposites is also proposed.

摘要

近年来,锂离子电池(LIBs)已广泛应用于汽车、采矿作业、太空应用、船舶和潜艇以及国防或军事应用中。作为阳极,商用碳或碳基材料存在一些关键问题,如充电容量和功率密度不足、工作电压低、形成自重、因枝晶形成导致短路倾向、设备升温等,这促使人们寻找碳的替代材料。过渡金属氧化物(TMOs)如氧化镍作为阳极可替代碳材料。然而,氧化镍存在一些局限性,如库仑效率低、循环稳定性差和离子电导率低。通过使用不同的纳米结构可以克服这些局限性。本研究综述了作为LIB阳极的氧化镍粘结剂复合纳米材料的电化学性能。这篇综述文章旨在概括纳米复合阳极的合成和表征参数,如比放电/充电容量、循环稳定性、倍率性能和循环能力。还提出了氧化镍纳米复合材料未来可能取得的进展概述。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6965/9457991/1688bd3c1b73/nanomaterials-12-02930-g005.jpg

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