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利用多元醇生产过程中产生的废磷酸进行施肥的可能性。

The Possibility of Using Waste Phosphates from the Production of Polyols for Fertilizing Purposes.

机构信息

Fertilizers Research Group, Łukasiewicz Research Network-New Chemical Syntheses Institute, Al. Tysiąclecia Państwa Polskiego 13a, 24-110 Puławy, Poland.

Department of Agricultural and Environmental Chemistry, University of Life Sciences in Lublin, Akademicka 13, 20-950 Lublin, Poland.

出版信息

Molecules. 2022 Sep 1;27(17):5632. doi: 10.3390/molecules27175632.

Abstract

The limited resources of phosphorus raw materials, which are located outside of Europe, make it necessary to obtain phosphorus from the waste stream. This is reflected in the new EU Regulation 2019/1009, which concerns making fertilizing products available on the market. Its main goal is to harmonize the standards for fertilizers obtained from organic or secondary raw materials in the EU and to create new opportunities for their production and sale. The fertilizer sector uses almost 90% of the phosphorus raw material, for which there is no substitute, and the demand for fertilizers is constantly growing, stimulated by the growing number of people. A substitute for expensive imported raw materials can be waste sodium-potassium phosphate from the production of polyols. This study analyzes the composition and form of waste from PCC Rokita S. A. from Brzeg Dolny in Poland, in terms of the possibility of using it in the production of fertilizers according to the new EU regulations. Research shows that it contains nearly 19% phosphorus, as well as potassium and sodium. Low-level impurities and low organic matter content classify it as a raw material for the production of inorganic fertilizers. Due to the high water content, the most advantageous form of its use is the production of fertilizers in the form of a suspension. A certain difficulty in the production of this type of fertilizer may be the layers of crystals of different sizes precipitating in the waste.

摘要

磷原料资源有限,且位于欧洲以外地区,这使得有必要从废物流中获取磷。这反映在新的欧盟法规 2019/1009 中,该法规涉及使肥料产品在市场上可用。其主要目标是协调欧盟内从有机或二级原料获得的肥料的标准,并为其生产和销售创造新的机会。肥料行业使用了近 90%的磷原料,这种原料没有替代品,而且对肥料的需求不断增长,这是由人口增长所刺激的。一种昂贵的进口原料替代品可以是多元醇生产过程中产生的废钠钾磷酸盐。本研究分析了来自波兰布热格多莱尼的 PCC Rokita S. A. 的废物的组成和形式,根据新的欧盟法规,研究了其在肥料生产中的使用可能性。研究表明,它含有近 19%的磷,以及钾和钠。低水平的杂质和低有机物含量将其归类为生产无机肥料的原料。由于含水量高,其最有利的使用形式是生产悬浮液形式的肥料。在生产这种类型的肥料时可能会遇到一定的困难,即不同大小的晶体层在废物中沉淀。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e8e/9457644/3427a49f2ef0/molecules-27-05632-g001.jpg

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