加压下化学战剂模拟物和农药的软性解毒。
Soft detoxification of chemical warfare agent simulants and pesticides under pressure.
机构信息
CNRS, Normandie Université, UNIROUEN, INSA Rouen, COBRA laboratory, F-76000 Rouen, France.
Departamento de Química, Universidade Federal do Paraná (UFPR), CP 19081, CEP 81531-990, Curitiba, PR, Brasil.
出版信息
Org Biomol Chem. 2022 Oct 5;20(38):7604-7608. doi: 10.1039/d2ob01217k.
The neutralisation of structurally varied chemical warfare agent simulants (blister and nerve agents) and pesticides (Paraoxon) with the assistance of high pressure is reported. Chloroethyl amines and sulfides (nitrogen and sulfur mustards), phosphonothioates (V-series nerve agents) and phosphates (pesticide) readily react with simple nucleophilic scavengers (alcohols, amines) at > 14 000 bar.
本文报道了在高压的辅助下，利用亲核试剂（醇类、胺类）对结构多样的化学战剂模拟物（糜烂性和神经性毒剂以及杀虫剂）进行中和的反应。氯乙胺和硫化物（氮芥和硫芥）、膦硫代酸盐（V 系列神经性毒剂）和磷酸盐（杀虫剂）在>14000 巴的压力下可与简单的亲核试剂迅速反应。
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