Tahzibi Haniyeh, Azizian Saeid, Szunerits Sabine, Boukherroub Rabah
Department of Physical Chemistry, Faculty of Chemistry, Bu-Ali Sina University, 65167 Hamedan, Iran.
Univ. Lille, CNRS, Centrale Lille, Univ. Polytechnique Hauts-de-France, UMR 8520, IEMN, F-59000 Lille, France.
ACS Appl Mater Interfaces. 2022 Oct 5;14(39):45013-45024. doi: 10.1021/acsami.2c12027. Epub 2022 Sep 23.
Transportation of bubbles in liquids in a controlled fashion is a challenging task and an important subject in numerous industrial processes, including elimination of corrosive gas bubbles in fluid transportation pipes, water electrolysis, reactions between gases, heat transfer, etc. Using superaerophilic surfaces represents a promising solution for bubble movement in a programmed way. Here, a novel and low-cost method is introduced for the preparation of Janus-faced carbon cloth (Janus-CC) using poly(dimethylsiloxane) (PDMS) coating and then burning one side of the carbon cloth/PDMS on an alcoholic burner. The results show that the superhydrophobic face behaves as a superaerophilic surface, while the superhydrophilic side is aerophobic underwater. Subsequently, the Janus-CC is applied for pumpless transport of underwater gas bubbles even under harsh conditions. The movement of gas bubbles on the surface of the Janus-CC is interpreted based on the formed gaseous film on the aerophilic side of the Janus-CC. Various applications of the prepared Janus-CC for underwater bubble transportation, such as underwater gas distributor, gas collector membrane, gas transport for chemical reactions, unidirectional gas membrane, and elimination of gas bubbles in transport pipe, are presented.
以可控方式在液体中输送气泡是一项具有挑战性的任务,也是众多工业过程中的一个重要课题,包括消除流体输送管道中的腐蚀性气泡、水电解、气体之间的反应、热传递等。使用超亲气表面是实现气泡按程序移动的一种有前景的解决方案。在此,介绍了一种新颖且低成本的方法来制备双面碳布(Janus-CC),即通过聚二甲基硅氧烷(PDMS)涂层,然后在酒精喷灯上燃烧碳布/PDMS的一侧。结果表明,超疏水表面表现为超亲气表面,而超亲水侧在水下是憎气的。随后,Janus-CC即使在恶劣条件下也可用于水下气泡的无泵输送。基于在Janus-CC亲气侧形成的气态膜来解释气泡在Janus-CC表面的移动。还介绍了所制备的Janus-CC在水下气泡输送方面的各种应用,如水下气体分配器、气体收集膜、化学反应中的气体输送、单向气体膜以及消除输送管道中的气泡。