Yusslee Eddy, Beskhyroun S
Auckland University of Technology (AUT), Auckland, 1010, New Zealand.
Sci Rep. 2022 Sep 23;12(1):15902. doi: 10.1038/s41598-022-19830-0.
One-part alkali-activated materials (AAMs) are developed to improve conventional two-part systems. One-part AAMs technology has been used in cement binders to produce concrete, mortar, and paste. Current research mainly focuses on synthesizing raw materials obtained from industrial and agricultural waste as the main aluminosilicate precursors of the cement binder for a concrete application. The one-part AAMs were reported to have higher early compressive strength at 7 days of age, contributed by its fast-setting time, mainly when the binder activates by a higher dosage of alkaline activator and containing OPC-rich. Due to bonding issues, single or combination, FA/GGBFS/MK precursors were reported as unsuitable for use as a concrete repair material. They were the reason for the lack of one-part AAMs application of mortar compared to concrete usage. This study was conducted to determine the potential of one-part AAMs used as concrete patch mortar by investigating its rheology and mechanical properties. The compressive strength of the mortar was tested under lab ambient temperature in the tropical climate country of Malaysia. The setting time of fresh mortar and bonding strength were set under controlled lab temperature. The one-part alkali-activated mortar was composed of hybrid aluminosilicate precursors between fly ash (FA), Ground Granulated Blast Furnace Slag (GGBFS) and ordinary Portland cement (OPC). A low alkaline activator of solid potassium carbonate was used for the geopolymerization process. Three types of solid admixtures were added to complete the composition of the new mix design. The experiment's outcome showed that the mortar composed with the combination of conventional Portland cement and industrial waste products has compressive and pull-off adherence strength that meets with Class R3-EN1504-3 standard for structural concrete repair materials requirement.
单组分碱激发材料(AAMs)是为改进传统双组分体系而开发的。单组分AAMs技术已用于水泥基粘结剂中以生产混凝土、砂浆和浆体。目前的研究主要集中在合成源自工农业废弃物的原材料,作为水泥基粘结剂的主要硅铝酸盐前驱体用于混凝土应用。据报道,单组分AAMs在7天龄期时具有较高的早期抗压强度,这得益于其快速凝结时间,主要是当粘结剂由较高剂量的碱性激发剂激发且含有高含量的普通硅酸盐水泥(OPC)时。由于粘结问题,据报道单独使用或组合使用的粉煤灰(FA)/粒化高炉矿渣(GGBFS)/偏高岭土(MK)前驱体不适合用作混凝土修补材料。这就是与混凝土应用相比,单组分AAMs在砂浆应用方面缺乏的原因。本研究旨在通过研究其流变学和力学性能来确定单组分AAMs用作混凝土修补砂浆的潜力。在马来西亚这个热带气候国家的实验室环境温度下测试了砂浆的抗压强度。在可控的实验室温度下测定了新拌砂浆的凝结时间和粘结强度。单组分碱激发砂浆由粉煤灰(FA)、粒化高炉矿渣(GGBFS)和普通硅酸盐水泥(OPC)之间的混合硅铝酸盐前驱体组成。使用低碱性的固体碳酸钾激发剂进行地质聚合过程。添加了三种类型的固体外加剂以完善新配合比设计的组成。实验结果表明,由传统波特兰水泥和工业废弃物组合而成的砂浆具有符合结构混凝土修补材料要求的R3-EN1504-3标准的抗压强度和拉拔粘结强度。