Zhang Bingwen, Deng Fenglin, Chen Xuejiao, Lv Xiaodong, Wang Jun
Fujian Key Laboratory of Functional Marine Sensing Materials, Center for Advanced Marine Materials and Smart Sensors, College of Material and Chemical Engineering, Minjiang University, Fuzhou 350108, People's Republic of China.
Key Laboratory of Magnetic Materials and Devices and Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, People's Republic of China.
J Phys Condens Matter. 2022 Oct 5;34(47). doi: 10.1088/1361-648X/ac9502.
The quantum anomalous Hall (QAH) effect has recently drawn great attention in spintronics with extraordinary property of chiral edge states without dissipation in absence of magnetic field. In MXhoneycomb Kagome lattice, numerous two-dimensional materials are predicted to be QAH insulators including metal oxides/sulfides and metal organic lattice. In this work, we proposed a general model to explain the mechanism of Dirac half metal with absence of spin orbital coupling and the nontrivial topological property with spin orbital coupling, which could be induced by combination of electron counting rule, crystal field effect anddxz,dyzorbitals hybridization. Based on the mechanism, we further predict that triphenyl-metal lattice M(CH)(= V, Nb, Ta) are all QAH insulators with high Curie temperature and large nontrivial band gap for triphenyl-Nb and triphenyl-Ta lattice.
量子反常霍尔(QAH)效应最近在自旋电子学中引起了极大关注,因为它具有手性边缘态的非凡特性,即在没有磁场的情况下无耗散。在MX蜂窝状 Kagome晶格中,预计许多二维材料都是QAH绝缘体,包括金属氧化物/硫化物和金属有机晶格。在这项工作中,我们提出了一个通用模型来解释在没有自旋轨道耦合时狄拉克半金属的机制以及有自旋轨道耦合时的非平凡拓扑性质,这可以由电子计数规则、晶体场效应和dxz、dyz轨道杂化的组合诱导产生。基于该机制,我们进一步预测三苯基金属晶格M(CH)(M = V、Nb、Ta)都是具有高居里温度的QAH绝缘体,并且对于三苯基-Nb和三苯基-Ta晶格具有大的非平凡带隙。