Key Laboratory of Research and Utilization of Ethnomedicinal Plant Resources of Hunan Province, Hunan Engineering Laboratory for Preparation Technology of Polyvinyl Alcohol Fiber Material, Huaihua University, Huaihua, 418000, PR China.
Hunan Province Key Laboratory for Antibody-based Drug and Intelligent Delivery System, Hunan University of Medicine, Huaihua, 418000, PR China.
Chem Rec. 2023 Feb;23(2):e202200212. doi: 10.1002/tcr.202200212. Epub 2022 Oct 4.
Dimension engineering plays a critical role in determining the electrocatalytic performance of catalysts towards water electrolysis since it is highly sensitive to the surface and interface properties. Bearing these considerations into mind, intensive efforts have been devoted to the rational dimension design and engineering, and many advanced nanocatalysts with multidimensions have been successfully fabricated. Aiming to provide more guidance for the fabrication of highly efficient noble-metal-based electrocatalysts, this review has focused on the recent progress in dimension engineering of noble-metal-based electrocatalysts towards water splitting, including the advanced engineering strategies, the application of noble-metal-based electrocatalysts with distinctive geometric structure from 0D to 1D, 2D, 3D, and multidimensions. In addition, the perspective insights and challenges of the dimension engineering in the noble-metal-based electrocatalysts is also systematically discussed.
维度工程在确定催化剂对水电解的电催化性能方面起着至关重要的作用,因为它对表面和界面性质非常敏感。考虑到这些因素,人们已经投入了大量精力进行合理的维度设计和工程,并且已经成功地制造了许多具有多维结构的先进纳米催化剂。为了为高效贵金属基电催化剂的制备提供更多指导,本综述重点介绍了贵金属基电催化剂在水分解方面的维度工程的最新进展,包括先进的工程策略,以及从 0D 到 1D、2D、3D 和多维具有独特几何结构的贵金属基电催化剂的应用。此外,还系统地讨论了贵金属基电催化剂中维度工程的透视见解和挑战。