Amine Manal, Mohammed Hoda A, Barakat Y
Processes Design & Development Department, Egyptian Petroleum Research Institute, Cairo, Egypt.
Analysis & Evaluation Department, Egyptian Petroleum Research Institute, Cairo, Egypt.
Sci Rep. 2022 Oct 13;12(1):17183. doi: 10.1038/s41598-022-21303-3.
Increased need for energy resources, as well as the urgent need to improve the air quality, have prompted further research to meet these challenges. Great efforts have been directed to reducing the impact of exhaust emissions. In literature, the effect of blending dimethyl carbonate (DMC) into fuel on engine performance and exhaust emissions has been investigated, and the obtained results were promising in decreasing exhaust emissions. In the present work, the effect of blending DMC into gasoline on the physicochemical properties was studied. Six fuel blends were prepared by blending base gasoline (G) with (0%, 2%, 4%, 6%, 8%, and 10%) of DMC. The volatility characteristics of the fuel blends were studied, such as the distillation curve, vapor pressure, and driveability index. The octane rating and the physicochemical properties of the fuel blends were also studied. The results of the study showed interesting findings that encourage refineries to be interested in this promising fuel additive. The results showed that the addition of DMC to gasoline has a very slight effect on the volatility of gasoline, unlike other oxygenated additives like short chain alcohols which cause a significant increase in the fuel volatility. The addition of DMC to gasoline causes an insignificant increase in the vapor pressure as the addition of 10% of DMC increases the vapor pressure by 2 kPa while it does not affect the values of T10, T50, and T90, which are the most important parameters of the distillation curve. The results also showed that its addition causes a remarkable increase in the octane rating. The RON has increased for the G-10DMC blend by about 5 points making the DMC a promising octane booster.
对能源资源需求的增加,以及改善空气质量的迫切需要,促使人们进行进一步研究以应对这些挑战。人们已付出巨大努力来减少废气排放的影响。在文献中,已研究了将碳酸二甲酯(DMC)混入燃料对发动机性能和废气排放的影响,所得结果在减少废气排放方面很有前景。在本研究中,研究了将DMC混入汽油对其物理化学性质的影响。通过将基础汽油(G)与0%、2%、4%、6%、8%和10%的DMC混合制备了六种燃料混合物。研究了燃料混合物的挥发性特征,如蒸馏曲线、蒸气压和驾驶性能指数。还研究了燃料混合物的辛烷值和物理化学性质。研究结果显示出有趣的发现,促使炼油厂对这种有前景的燃料添加剂产生兴趣。结果表明,与其他含氧添加剂(如短链醇会导致燃料挥发性显著增加)不同,向汽油中添加DMC对汽油挥发性的影响非常小。向汽油中添加DMC会使蒸气压有微不足道的增加,因为添加10%的DMC会使蒸气压增加2kPa,而这并不影响蒸馏曲线中最重要的参数T10、T50和T90的值。结果还表明,添加DMC会使辛烷值显著提高。G - 10DMC混合物的研究法辛烷值(RON)提高了约5个点,使DMC成为一种有前景的辛烷值提升剂。