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离子液体 [bmim] [TFSI] 模板 Na-X 沸石用于吸附 (Cd, Zn) 和染料 (AR, R6)。

Ionic liquid [bmim] [TFSI] templated Na-X zeolite for the adsorption of (Cd, Zn), and dyes (AR, R6).

机构信息

Department of Safety, Health, and Environmental Engineering, National Yunlin University of Science and Technology, Douliou City, Yunlin, 64002, Taiwan.

Research Centre for Soil & Water Resources and Natural Disaster Prevention (SWAN), National Yunlin University of Science & Technology, Douliou, 64002, Taiwan, ROC.

出版信息

Environ Res. 2023 Jan 1;216(Pt 2):114525. doi: 10.1016/j.envres.2022.114525. Epub 2022 Oct 13.

Abstract

1-butyl-3-methylimidazolium bis(triflouromethylsufonyl)imide functionalization to Na-X zeolite (IFZ) is the primary goal of this study in order to evaluate its ability to remove heavy metals (Cd), (Zn), dyes Rhodamine 6G (R6), and Alizarin Red S (AR) from aqueous streams. IFZ was thoroughly examined using analytical techniques XRD, BET, FE-SEM, and FTIR, to better understand its physical and chemical properties. The surface area and the volume of pores (IFZ; 19.93 m/g, 0.0544 cm/g) were reduced in comparison to the parent zeolite (Na-X; 63.92 m/g, 0.0884 cm/g). According to SEM, the crystal structure of the zeolite (Na-X) has not been significantly altered by XRD analysis. The mechanism, kinetics, isotherms, and thermodynamic properties of adsorption were all studied using batch adsorption experiments under various operating conditions. IFZ adsorbs dyes (AR; 76.33 mg/g, R6; 65.85 mg/g) better than metal ions (Cd; 30.68 mg/g, Zn; 41.53 mg/g) in acidic conditions. The Langmuir isotherm and pseudo-second order models were found to be the most accurate models for equilibrium data. Adsorption is endothermic and spontaneous, as revealed by the thermodynamics of the process. The IFZ can be used in three (Cd), two (Zn), four (AR), and five (R6) cycles of desorption and regeneration. For these reasons, IL-modified zeolite can be used to remove multiple types of pollutants from water in one simple step.

摘要

本研究的主要目的是对 1-丁基-3-甲基咪唑双(三氟甲基磺酰基)亚胺功能化钠-X 沸石(IFZ)进行功能化,以评估其从水溶液中去除重金属(Cd)、(Zn)、染料罗丹明 6G(R6)和茜素红 S(AR)的能力。通过 XRD、BET、FE-SEM 和 FTIR 等分析技术对 IFZ 进行了全面研究,以更好地了解其物理和化学性质。与母体沸石(Na-X)相比,IFZ 的表面积(IFZ:19.93 m/g,0.0544 cm/g)和孔体积(IFZ:19.93 m/g,0.0544 cm/g)减小。根据 SEM 分析,XRD 分析并未显著改变沸石(Na-X)的晶体结构。在不同操作条件下通过批量吸附实验研究了吸附的机理、动力学、等温线和热力学性质。IFZ 在酸性条件下对染料(AR:76.33 mg/g,R6:65.85 mg/g)的吸附优于金属离子(Cd:30.68 mg/g,Zn:41.53 mg/g)。结果表明,Langmuir 等温线和准二级动力学模型最适合描述平衡数据。吸附是吸热和自发的,这反映了过程的热力学性质。IFZ 可以在三次(Cd)、两次(Zn)、四次(AR)和五次(R6)的脱附和再生循环中使用。由于这些原因,IL 修饰沸石可以在一个简单的步骤中去除水中的多种类型的污染物。

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