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使用新型有机硅单体实现的低电压快速响应聚合物稳定蓝相液晶。

Low-voltage and fast-response polymer-stabilized blue-phase liquid crystals achieved using a new organosilicone monomer.

作者信息

Bo Shuhui, Chen Baohui, Zhu Dongping, Feng Shuai, Chen Zhuo

机构信息

Optoelectronics Research Centre, School of Science, Minzu University of China, Beijing, 100081, P. R. China.

Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.

出版信息

Soft Matter. 2022 Nov 2;18(42):8188-8193. doi: 10.1039/d2sm01075e.

Abstract

In this paper, two types of polymer-stabilized blue-phase liquid crystals (PS-BPLCs) with different monomers were designed and prepared. The morphology, temperature range and electro-optical properties of the blue phases were studied and discussed. The temperature range of both types of PS-BPLC is greater than 110 °C, and both samples can be stabilized well at room temperature. The organosilicone monomer 3-methacryloxypropyltrimethoxysilane (KH570), which contains double bonds, was introduced to a blue-phase system for the first time. Regarding the electro-optical performance, the on-state voltage of the PS-BPLCs with the KH570 monomer is reduced to 30 V compared with traditional C12A monomer systems in which the on-state voltage is 75 V at 458 nm. Meanwhile, a fast response and suppressed hysteresis are obtained. These results are helpful to the application of displays and photonic devices.

摘要

本文设计并制备了两种含不同单体的聚合物稳定蓝相液晶(PS - BPLCs)。研究并讨论了蓝相的形态、温度范围和电光特性。两种类型的PS - BPLC的温度范围均大于110℃,且两个样品在室温下都能很好地稳定。首次将含双键的有机硅单体3 - 甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)引入蓝相体系。在电光性能方面,含KH570单体的PS - BPLCs的导通电压在458nm处降至30V,而传统C12A单体体系在该波长下的导通电压为75V。同时,获得了快速响应和抑制的滞后现象。这些结果有助于显示器和光子器件的应用。

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