双（苯并[h]喹啉-10-醇根合-κO）溴化锰（III）
Bis(benzo[]quinolin-10-olato-κ ,)bromidomanganese(III).
作者信息
Papa Veronica, Spannenberg Anke, Beller Matthias, Junge Kathrin
机构信息
Leibniz-Institut für Katalyse e. V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany.
出版信息
IUCrdata. 2020 Dec 4;5(Pt 12):x201570. doi: 10.1107/S2414314620015709. eCollection 2020 Dec.
Abstract
The title compound, [MnBr(CHNO)], consists of a manganese(III) atom, which is coordinated by one bromido and two benzo[]quinolin-10-olato ligands. The Mn complex exhibits a distorted square-pyramidal coordination geometry with the Br ligand in the apical position. Neighbouring complexes are held together by π-π inter-actions and weak C-H⋯Br hydrogen bonds.
摘要
标题化合物[MnBr(CHNO)]由一个锰(III)原子组成，该原子由一个溴配体和两个苯并[]喹啉-10-醇配体配位。锰配合物呈现出扭曲的四方锥配位几何构型，其中溴配体处于顶端位置。相邻的配合物通过π-π相互作用和弱的C-H⋯Br氢键结合在一起。
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