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聚[双-(μ-，-二甲基甲酰胺-κ:)]双-(μ-噻吩-2,5-二羧酸根合-κ:':'':''')二钴(II)]

Poly[bis-(μ-,-di-methyl-formamide-κ :)bis-(μ-thio-phene-2,5-di-carboxyl-ato-κ :':'':''')dicobalt(II)].

作者信息

Ren Ji-Yun, Huang Rou, Yin Zheng, Cao Li-Hui

机构信息

College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, People's Republic of China.

出版信息

IUCrdata. 2022 Aug 12;7(Pt 8):x220775. doi: 10.1107/S2414314622007751. eCollection 2022 Aug.

DOI:10.1107/S2414314622007751
PMID:36340975
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9635415/
Abstract

The asymmetric unit of the title three-dimensional metal-organic hybrid compound, [Co(CHOS)(CHNO)] , comprises two cobalt(II) cations, one residing on a twofold axis and the other on a centre of inversion, one thio-phene-2,5-di-carboxyl-ate (tdc) ligand and one coordinating di-methyl-formamide (DMF) solvent mol-ecule. Both of the cobalt(II) cations exhibit an octa-hedral coordination environment from the four carboxyl O atoms of the tdc anions in a - : : : fashion and two O atoms from DMF. A pair of carboxyl O atoms and one DMF molecule connect the adjacent cobalt(II) cations into an infinite chain, leading to a rod-spacer framework with rhombus-window channels, yet no residual solvent-accessible voids are present because the coordinating DMF molecules are oriented into the potential channels.

摘要

标题三维金属有机杂化化合物[Co(CHOS)(CHNO)]的不对称单元包含两个钴(II)阳离子，一个位于二重轴上，另一个位于对称中心上，一个噻吩-2,5-二羧酸酯(tdc)配体和一个配位二甲基甲酰胺(DMF)溶剂分子。两个钴(II)阳离子均呈现八面体配位环境，来自tdc阴离子的四个羧基O原子以 - : : : 方式配位，以及来自DMF的两个O原子。一对羧基O原子和一个DMF分子将相邻的钴(II)阳离子连接成无限链，形成具有菱形窗口通道的棒状间隔框架，但由于配位DMF分子定向进入潜在通道，不存在残留的溶剂可及空隙。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f70c/9635415/79718b34ad3e/x-07-x220775-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f70c/9635415/4568637a00ff/x-07-x220775-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f70c/9635415/79718b34ad3e/x-07-x220775-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f70c/9635415/4568637a00ff/x-07-x220775-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f70c/9635415/79718b34ad3e/x-07-x220775-fig2.jpg

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