Wu Ying, Xu Lijie, Xia Changlei, Gan Lu
College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, Jiangsu, People's Republic of China.
College of Biology and the Environment, Nanjing Forestry University, Nanjing 210037, Jiangsu, People's Republic of China.
Int J Biol Macromol. 2022 Dec 31;223(Pt A):184-192. doi: 10.1016/j.ijbiomac.2022.10.266. Epub 2022 Nov 4.
In this study, ethyl cellulose was used as the second-phase polymer blended with polyurethane to make nanofibrous membrane as antibacterial strain sensor. The results indicated that ethyl cellulose could regulate the morphology of polyurethane through strong hydrogen bonding, which observably enhanced the nanofiber uniformity of polyurethane. Furthermore, rigid cellulose also remarkably improved the mechanical strength and thermal stability of the nanofibrous membrane. After being coated with silver nanoparticles and carbon nanotubes assisted by polydopamine (PDA), the membrane with outstanding bacteria inhibition performance exhibited outstanding sensitivity toward external mechanical stretching, as well as real-time motion of human body parts. The conductive composite membrane possessed sensitive and regular resistance feedback to 100 cycles of varied human motions. The cellulose in the nanofiber structure ensured the shape recovery and longtime use stability of the membrane. This study proposed a novel thinking for the construction of high performance strain sensor by rational introduction of rigid polysaccharide into the polymer matrix.
在本研究中,乙基纤维素被用作与聚氨酯共混的第二相聚合物,以制备作为抗菌应变传感器的纳米纤维膜。结果表明,乙基纤维素可通过强氢键作用调节聚氨酯的形态,显著提高聚氨酯纳米纤维的均匀性。此外,刚性纤维素还显著提高了纳米纤维膜的机械强度和热稳定性。在聚多巴胺(PDA)辅助下涂覆银纳米颗粒和碳纳米管后,具有优异抑菌性能的该膜对外界机械拉伸以及人体部位的实时运动表现出出色的灵敏度。该导电复合膜对100次不同人体运动具有灵敏且规律的电阻反馈。纳米纤维结构中的纤维素确保了膜的形状恢复和长期使用稳定性。本研究通过将刚性多糖合理引入聚合物基体,为构建高性能应变传感器提出了一种新思路。