A multi-chromic supercapacitor of high coloration efficiency integrating a MOF-derived VO electrode.

Modern technological trends in smart electronic devices demand more intelligent automation. Simultaneous integration of energy storage and multicolor electrochromism in a single device improves user-device interfacing based on a salient human-readable output. In this work, primarily metal-organic framework (MOF) derived VO was synthesized which, as an electrochromic material, shows high optical modulation of 35% at 485 nm, with very fast switching speeds (2.9/3.4 s for coloring/bleaching). The multiple coloration states of the VO electrode make it worthy for further integration as a smart negative electrode in a multicolored electrochromic asymmetric supercapacitor, where the electrochromic polyaniline electrode serves as the counter electrode. The device demonstrates a high coloration efficiency of 137.2 cm C and an areal capacitance of 12.27 mF cm and an energy density of 2.21 × 10 mW h cm at a current density of 0.05 mA cm. By virtue of its different chromatic states during charging and discharging, smart visual tracking of the state of charge of the supercapacitor can be realized. Such a design of energy storage devices will have promising practical application in futuristic smart multifunctional electronic devices.