Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Koriyama, Fukushima, Japan.
Center for Measurement Standards (CMS), Industrial Technology Research Institute (ITRI), Hsinchu, Taiwan, R.O.C.
PLoS One. 2022 Nov 17;17(11):e0277768. doi: 10.1371/journal.pone.0277768. eCollection 2022.
Various cell crack modes (with or without electrically inactive cell areas) can be induced in crystalline silicon photovoltaic (PV) cells within a PV module through natural thermomechanical stressors such as strong winds, heavy snow, and large hailstones. Although degradation in the performance of PV modules by cell cracks has been reported occasionally, the mode-dependent evolutions in the electrical signatures of cracks have not yet been elucidated. In this study, we propose that the reduction of the time constant in the AC impedance spectra, which is caused by the elevation of minority-carrier recombination in the p-n junction of a PV cell, is a ubiquitous signature of cracked PV cells encapsulated in a commercially available PV module. Several other characteristics derived from the illuminated current-voltage (I-V) and dark I-V data significantly evolved only in PV cells with inactive cell areas. We also propose that the evaluation by carrier recombination is a crucial diagnostic technique for detecting all crack modes, including microcracks, in wafer-based PV modules.
各种电池裂纹模式(带或不带电非活性电池区域)可在光伏模块内的晶体硅光伏(PV)电池中通过自然热机械胁迫诱导,如强风、大雪和大冰雹。尽管偶尔有报道称电池裂纹会导致 PV 模块性能下降,但裂纹电特性的模式相关演化尚未阐明。在本研究中,我们提出交流阻抗谱中时间常数的降低,这是由光伏电池 p-n 结中少数载流子复合的升高引起的,是封装在市售光伏模块中的裂纹光伏电池的普遍特征。从受光电流-电压(I-V)和暗 I-V 数据得出的其他几个特征仅在具有非活性电池区域的光伏电池中显著演变。我们还提出,载流子复合的评估是检测所有裂纹模式(包括晶片基 PV 模块中的微裂纹)的关键诊断技术。