Design of an S-scheme photo-catalyst utilizing a Cu-doped perovskite and MOF-5 for simultaneous degradation of organic pollutants under LED light irradiation: Application of EXRSM method for spectra separation and BBD-RSM modeling.

Heterojunction photo-catalysts have attracted significant attention in solar energy conversion due to their ability to reduce suppressing electron-hole pairs and improve catalytic capability. Herein, we designed an S-scheme photo-catalyst by encapsulating a Cu-doped perovskite inside the pores of MOF-5 for the first time, exhibiting excellent efficiency in a pollutant degradation process. The pristine MOF cannot act in the visible light region because of its wide bandgap. However, the encapsulation modified its bandgap and but also increased its photo-catalytic activity. Simultaneous photo-degradation of two organic contaminants, methylene blue (MB) and paracetamol (PA), was investigated to evaluate the catalytic activity of this composite. As a challenge, the UV-vis spectra of PA strongly overlapped with MB in a binary mixture preventing direct measurement of its concentration without previous separation via conventional methodologies. Hence, we used a simple and fast technique called the extended ratio subtraction method (EXRSM) to separate their absorption spectra. The statistical investigations established that it could resolve the issue of signal overlapping. Also, a statistical approach, Box-Behnken (BBD-RSM), was used to model and optimize the degradation process providing a better way to explain the effect and interactions of main parameters on degradation efficiency. Now, an empirical model for each pollutant can make a relationship between them. The photo-degradation yield was obtained at 67.12% and 87.96% for PA and MB, respectively, under optimum conditions. Furthermore, the kinetics and mechanism of reaction were investigated, and the results revealed that it follows a pseudo-first-order model for each pollutant.