作为有机半导体的噻吩并并苯类似物的磷杂并苯。
Phosphaacene as a structural analogue of thienoacenes for organic semiconductors.
机构信息
Division of Materials Science, Nara Institution of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma, Nara, 630-0192, Japan.
The Institute of Scientific and Industrial Research (SANKEN), Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan.
出版信息
Chem Commun (Camb). 2022 Dec 8;58(98):13576-13579. doi: 10.1039/d2cc05122b.
An air-stable λ-phosphinine-containing polycyclic aromatic compound without steric protection was synthesized and its charge transport properties were evaluated, which revealed moderate hole mobility. This research is the first experimental demonstration of the organic electronic applications of low-coordinate phosphorus compounds.
合成了一种不含空间位阻保护的空气稳定的含λ-膦烯的多环芳烃化合物，并对其电荷输运性能进行了评价，结果表明其具有中等的空穴迁移率。这项研究首次实验证明了低配位磷化合物在有机电子领域的应用。
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