Department of Civil and Environmental Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, United States.
Department of Engineering and Public Policy, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, United States.
Environ Sci Technol. 2023 Jan 10;57(1):842-851. doi: 10.1021/acs.est.2c06614. Epub 2022 Dec 23.
Following an exceedance of the lead action level for drinking water in 2016, the Pittsburgh Water and Sewer Authority (PWSA) undertook two sampling programs: the required biannual Lead and Copper Rule (LCR) compliance testing and a home sampling program based on customer requests. The LCR sampling results, at locations expected to be elevated when corrosion is not well controlled, had higher concentrations than customer-requested homes, with 90th percentile values for the LCR sites exceeding the action level through 2019 (except for June 2018). Customer-requested concentrations showed greater variability, with the median lead concentration for customer-requested samples below detection for each year of sampling, suggesting only some homes show elevated lead when corrosion control is not fully effective. Corrosion control adjustments brought the utility back into compliance in 2020 (LCR 90th percentile of 5.1 ppb in June 2020); customer-requested sampling after the addition of orthophosphate indicated below detection levels for 59% of samples. Monte Carlo simulations indicate LCR samples do not all represent high lead risk sites, and the application of corrosion control more significantly affects higher lead concentration sites. Broader water quality sampling provides information about specific homes but is not well suited to assessing the efficacy of corrosion control efforts by utilities.
在 2016 年饮用水铅超标之后,匹兹堡水和污水管理局(PWSA)开展了两项抽样计划:按要求进行的半年度《铅和铜规则》(LCR)合规性测试,以及根据客户要求开展的家庭抽样计划。在腐蚀控制不佳时预计会升高的位置,LCR 抽样结果的浓度高于客户要求的家庭,LCR 地点的第 90 个百分位数值在 2019 年之前一直超过行动水平(2018 年 6 月除外)。客户要求的浓度变化更大,客户要求的样本中位数铅浓度每年都低于检测值,这表明只有部分家庭在腐蚀控制不完全有效时显示出铅含量升高。腐蚀控制调整使该公用事业公司在 2020 年恢复合规(2020 年 6 月 LCR 的第 90 个百分位数为 5.1ppb);在添加正磷酸盐后进行的客户要求抽样中,有 59%的样本低于检测水平。蒙特卡罗模拟表明,LCR 样本并不代表所有高铅风险点,而腐蚀控制的应用更显著地影响高浓度铅点。更广泛的水质抽样提供了有关特定家庭的信息,但不适合评估公用事业公司腐蚀控制工作的效果。