CUTEC Research Center for Environmental Technologies, Clausthal University of Technology, 38678 Clausthal-Zellerfeld, Germany E-mail:
Institute of Chemical and Electrochemical Process Engineering, Clausthal University of Technology, 38678 Clausthal-Zellerfeld, Germany.
Water Sci Technol. 2022 Dec;86(12):3236-3247. doi: 10.2166/wst.2022.390.
Using electrolysis systems to degrade organics in wastewater encourages this technique to remove micropollutants (MPs) in different types of water. In this work, a cell consisting of an anode as a boron-doped diamond (BDD) electrode combined with a gas diffusion (GDE) cathode without a separator showed that MPs degradation can be effectively achieved. Investigating different operating parameters, it was stated that applying a low current density (2 mA/cm) and setting the Reynolds number of the electrolyte flow through the cell at the laminar range raised the treatment time by 3-fold at the same energy demand. This arrangement increased the MPs removal. Some substances like diclofenac were removed up to 84% at a longer treatment time of 180 min coupled with an increase in energy demand. The results at the mentioned parameters indicated an adequate generation rate of radicals needed to remove MPs and the oxidation reactions were promoted. The results show high potential to the investigated electrolysis system in removing MPs in wastewater under considering the need for further reduction of the energy demand.
利用电解系统降解废水中的有机物,促使该技术能够去除不同类型水中的微量污染物 (MPs)。在这项工作中,由掺硼金刚石 (BDD) 电极作为阳极和气体扩散 (GDE) 阴极组成的电池,没有使用隔板,表明可以有效地实现 MPs 降解。研究不同的操作参数表明,施加低电流密度 (2 mA/cm) 并将电解质在电池中流动的雷诺数设置在层流范围内,可以在相同的能量需求下将处理时间延长 3 倍。这种布置提高了 MPs 的去除率。某些物质,如双氯芬酸,在 180 分钟的更长处理时间和能量需求增加的情况下,去除率高达 84%。在所述参数下的结果表明,需要进一步降低能量需求,以去除 MPs 和促进氧化反应,需要足够的自由基生成速率。结果表明,在考虑进一步降低能量需求的情况下,该电解系统在去除废水中的 MPs 方面具有很高的潜力。