Sun Shanshan, Zhao Minglin, Wang Qingwei, Xue Shujie, Huang Qinghong, Yu Nengfei, Wu Yuping
Nanjing Tech University, Nanjing, Jiangsu, 211816, P. R. China.
Small. 2023 Mar;19(12):e2205835. doi: 10.1002/smll.202205835. Epub 2023 Jan 12.
It is vital to create flexible batteries as power sources to suit the needs of flexible electronic devices because they are widely employed in wearable and portable electronics. The direct methanol fuel cell (DMFC) is a desirable alternative portable energy source since it is a clean, safe, and high energy density cell. The traditional DMFC in mechanical assembly and its unbending property, however, prevent it from being employed in flexible electrical devices. In this study, the flexible membrane electrode assembly (MEA) with superior electrical conductivity and nanoscale TiC-modified carbon cloth (TiC/CC) is used as supporting layer. Additionally, solid methanol fuels used in the manufacturing of flexible all-solid-state DMFC have the advantages of being tiny, light, and having high energy density. Furthermore, the DMFC's placement and bending angle have little effect on its performance, suggesting that DMFC is appropriate for flexible portable energy. The flexible all-solid-state DMFC's power density can reach 14.06 mW cm , and after 50 bends at 60°, its voltage loss can be disregarded. The flexible all-solid DMFC has an energy density that is 777.78 Wh Kg higher than flexible lithium-ion batteries, which is advantageous for the commercialization of flexible electronic products.
由于柔性电子设备广泛应用于可穿戴和便携式电子产品中,因此制造柔性电池作为电源以满足其需求至关重要。直接甲醇燃料电池(DMFC)是一种理想的替代便携式能源,因为它是一种清洁、安全且能量密度高的电池。然而,传统DMFC的机械组装方式及其不可弯曲的特性使其无法应用于柔性电子设备。在本研究中,具有优异导电性的柔性膜电极组件(MEA)和纳米级TiC改性碳布(TiC/CC)被用作支撑层。此外,用于制造柔性全固态DMFC的固态甲醇燃料具有体积小、重量轻和能量密度高的优点。此外,DMFC的放置方式和弯曲角度对其性能影响很小,这表明DMFC适用于柔性便携式能源。柔性全固态DMFC的功率密度可达14.06 mW/cm²,在60°下弯曲50次后,其电压损失可忽略不计。柔性全固态DMFC的能量密度比柔性锂离子电池高777.78 Wh/Kg,这有利于柔性电子产品的商业化。