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漆酚改性环氧丙烯酸酯作为紫外光喷涂东方大漆油墨。

Urushiol modified epoxy acrylate as UV spray painting oriental lacquer ink.

作者信息

Wu Lujing, Zhu Wenkai, Li Zequn, Li Huimin, Xu Jing, Li Song, Chen Meiling

机构信息

Academy of Art, Jinling Institute of Technology Nanjing 211199 China

College of Chemistry and Materials Engineering, Zhejiang A & F University Hangzhou 311300 China

出版信息

RSC Adv. 2023 Jan 4;13(2):1106-1114. doi: 10.1039/d2ra06685h. eCollection 2023 Jan 3.

Abstract

As a natural "water-based" polymer composite material, oriental lacquer is often referred to as the "king of coatings" and is used as a coating in the defense industry, chemical industry, petroleum industry, metallurgy and mining industry, textile painting and dyeing industry, pharmaceutical industry, as well as the protection of ancient buildings and cultural relics. However, the development of modern industrialization is greatly hindered by the high viscosity of oriental lacquer, the difficulty of spraying, the long drying cycle, and the seriousness of allergenicity. Herein, based on the principle of oriental lacquer and the characteristics of prepolymer in ink, we developed a new prepolymer for modulating UV oriental lacquer ink and explored the feasibility of using it as a raw material for UV spray painting. In this study, lacquer phenol was extracted from oriental lacquer and modified with epoxy acrylate by a simple mechanical compounding method to obtain lacquer epoxy acrylate. Moreover, the UV spray painting oriental lacquer ink was also prepared by using it as the main film-forming substance. The orthogonal experiment method was used to optimize the best formulation of UV spray painting oriental lacquer ink by using nozzle passability, viscosity and curing time as test indexes. Meanwhile, the film properties of UV spray painting oriental lacquer inks were also evaluated. The test results show that the UV spray painting oriental lacquer ink prepared with urushiol epoxy acrylate has better dispersion, excellent paint film performance, and solves the problem that oriental lacquer cannot be printed. This present work shows that urushiol epoxy acrylate as a new type of prepolymer has broad application prospects in the actual preparation of UV inks.

摘要

作为一种天然的“水性”高分子复合材料,大漆常被称为“涂料之王”,并被应用于国防工业、化学工业、石油工业、冶金矿业、纺织印染工业、制药工业以及古建筑和文物保护等领域。然而,大漆的高粘度、喷涂困难、干燥周期长以及致敏性严重等问题极大地阻碍了现代工业化的发展。在此,基于大漆的原理和油墨中预聚物的特性,我们开发了一种用于调制紫外光固化大漆油墨的新型预聚物,并探索了将其用作紫外光固化喷涂原料的可行性。在本研究中,从大漆中提取漆酚,并通过简单的机械共混方法用环氧丙烯酸酯对其进行改性,得到漆酚环氧丙烯酸酯。此外,以其作为主要成膜物质制备了紫外光固化喷涂大漆油墨。采用正交试验法,以喷头通过率、粘度和固化时间为测试指标,优化了紫外光固化喷涂大漆油墨的最佳配方。同时,还对紫外光固化喷涂大漆油墨的漆膜性能进行了评价。测试结果表明,用漆酚环氧丙烯酸酯制备的紫外光固化喷涂大漆油墨具有较好的分散性、优异的漆膜性能,解决了大漆无法进行印刷的问题。本研究表明,漆酚环氧丙烯酸酯作为一种新型预聚物在紫外光固化油墨的实际制备中具有广阔的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/44ba/9811650/99f9f06f9ed3/d2ra06685h-f1.jpg

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