Zhang Rui, Wu Kai, Xie Dezhi, Wang Jianyun
Department of Civil Engineering, Xi'an Jiaotong University, Xi'an, 710049, China.
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai, 201804, China.
Appl Microbiol Biotechnol. 2023 Mar;107(5-6):1525-1536. doi: 10.1007/s00253-023-12394-7. Epub 2023 Jan 28.
The recycled concrete aggregates have high porosity and water absorption, which hinders their utilization in concrete production. Microbial-induced calcium carbonate precipitation was regarded as a very promising method for strengthening recycled aggregates. However, the uneven distribution of CaCO on surface of aggregates encountered in the current bio-deposition treatment weakened the efficiency, especially in the aspect of the decrease of water absorption. Therefore, this study innovatively applied a sodium alginate aided bio-deposition treatment to improve the uniform distribution of biogenic CaCO. The principle was that sodium alginate was used to uniformly "fix" the bio-agents (urea or bacterial cells) on the surface of recycled aggregates, which was supposed to promote the uniform in-situ precipitation of CaCO on the surface of aggregates, and hence effectively blocking surface pores, and reducing the water absorption of the aggregates. Two concentrations of sodium alginate (0.2w% and 0.5w%) and four sodium alginate aided bio-deposition treatments were studied. It was found that CaCO (a mass increase of 4.05%) was formed on the aggregates after the suitable sodium alginate aided bio-deposition treatment. The participation of sodium alginate made CaCO uniformly deposited on full surface of the aggregates, resulting in a significant decrease (42.10%) of water absorption. The biogenic CaCO showed limited mass loss under ultrasonic attack, indicated a strong cohesion and bonding strength with aggregates. The results demonstrated that sodium alginate-aided bio-deposition treatment can enhance the efficiency, which was beneficial to improve the quality of recycled aggregates and their utilization of recycled aggregates in concrete production. KEY POINTS: • The SA-aided bio-treatment promoted the distribution uniformity of CaCO on aggregates. • The water absorption of aggregates decreased by 42.10%. • The formed CaCO showed excellent cohesion and adhesion.
再生混凝土骨料具有较高的孔隙率和吸水率,这阻碍了它们在混凝土生产中的应用。微生物诱导碳酸钙沉淀被认为是一种非常有前景的增强再生骨料的方法。然而,目前生物沉积处理中骨料表面碳酸钙分布不均,削弱了其效果,尤其是在降低吸水率方面。因此,本研究创新性地应用海藻酸钠辅助生物沉积处理来改善生物成因碳酸钙的均匀分布。其原理是利用海藻酸钠将生物制剂(尿素或细菌细胞)均匀地“固定”在再生骨料表面,这有望促进碳酸钙在骨料表面均匀原位沉淀,从而有效堵塞表面孔隙,降低骨料的吸水率。研究了两种浓度的海藻酸钠(0.2w%和0.5w%)以及四种海藻酸钠辅助生物沉积处理。结果发现,经过合适的海藻酸钠辅助生物沉积处理后,骨料上形成了碳酸钙(质量增加4.05%)。海藻酸钠的参与使碳酸钙均匀沉积在骨料整个表面,导致吸水率显著降低(42.10%)。生物成因碳酸钙在超声作用下质量损失有限,表明其与骨料具有很强的内聚力和粘结强度。结果表明,海藻酸钠辅助生物沉积处理可以提高效率,这有利于提高再生骨料的质量及其在混凝土生产中的利用率。要点:• 海藻酸钠辅助生物处理促进了碳酸钙在骨料上的分布均匀性。• 骨料吸水率降低了42.10%。• 形成的碳酸钙表现出优异的内聚力和附着力。