Linking downstream river water quality to urbanization signatures in subtropical climate.

Urbanization has several hydro-ecological effects on receiving waters. Hence, understanding how urbanization influences river water quality is essential for proper river management. However, an inappropriate approach that correlates urbanization signatures with water quality may result in spurious correlations. This study aimed to investigate the relationship of urbanization signatures with two key pollutants of stream flows: nutrients and pathogens. In contrast to the commonly used approaches that are based on economic or demographic metrics, our approach represents urbanization signatures using related anthropogenic activities and evaluates the effect of such activities on water quality parameters. The approach was also applied to evaluate the impacts of urbanization on nutrient and pathogen trends in the river waters of Hong Kong. The data were collected for the period of 1986-2020 from the Environmental Protection Department and monthly measurements were performed. Total nitrogen (TN), total phosphorus (TP), Escherichia. coli (E. coli), and fecal coliforms (FC) showed consistently decreasing trends. However, the long-term seasonality of nutrients differed from that of pathogens. TP and TN exhibited homogenous seasonality with an approximately sinusoidal relationship from January to December, whereas the seasonality of pathogens was more complex and not dependent on river flow dilution effects. Additionally, urbanization impacts on station nutrients and pathogen characteristics were found to be unevenly distributed; under high water temperatures, nutrient concentrations were found to be decreased because of the rainfall dilution effect on river flows. Both urban point and diffuse sources of pollution significantly contributed to nutrient pollution in rivers. Furthermore, the concentrations of FC were not highly influenced by suspended solids, and dissolved oxygen was negatively correlated with all pathogens. Furthermore, the river flow rate was found to improve the water quality in terms of both nutrients and pathogens; urban point source pollution and river temperature alteration were shown to mainly contribute to seasonal variations in both nutrients and pathogens.