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基体选择和统一过程对柔性基板上导电石墨烯层关键参数的影响

The Influence of the Matrix Selection and the Unification Process on the Key Parameters of the Conductive Graphene Layers on a Flexible Substrate.

作者信息

Lepak-Kuc Sandra, Nowicki Łukasz, Janczak Daniel, Jakubowska Małgorzata

机构信息

Institute of Metrology and Biomedical Engineering, Faculty of Mechatronics, Warsaw University of Technology, Sw. Andrzeja Boboli 8, 02-525 Warsaw, Poland.

Centre for Advanced Materials and Technologies (CEZAMAT), Warsaw University of Technology, 02-822 Warsaw, Poland.

出版信息

Materials (Basel). 2023 Jan 31;16(3):1238. doi: 10.3390/ma16031238.

DOI:10.3390/ma16031238
PMID:36770245
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9921362/
Abstract

Screen-printed graphene layers on flexible substrates are one of the most advanced printed electronics developments of recent years. Obtaining thin, flexible, highly conductive components, whose applications are increasingly directed towards biomedical engineering and even medicine, requires an in-depth understanding of the correct choice of materials and procedures. Our work was aimed at investigating the influence of homogenisation in the triple rolling process over pastes dedicated to the screen printing technology, on their rheological parameters and the properties of the prints. The effect of selecting a suitable polymer matrix and different packing of graphene flakes was evaluated. Several studies were carried out, which can provide an excellent knowledge base in the context of graphene screen-printing pastes. Paste rheology, printability, path thickness, sheet resistance and adhesion to the substrate were investigated. Selected layers were also subjected to SEM imaging.

摘要

柔性基板上的丝网印刷石墨烯层是近年来最先进的印刷电子技术发展成果之一。要获得薄的、柔性的、高导电性的组件,其应用越来越多地指向生物医学工程甚至医学领域,就需要深入了解材料和工艺的正确选择。我们的工作旨在研究三辊轧制过程中的均化对用于丝网印刷技术的浆料的影响,以及对其流变参数和印刷品性能的影响。评估了选择合适的聚合物基体和不同石墨烯薄片堆积方式的效果。进行了多项研究,这些研究可以为石墨烯丝网印刷浆料提供一个优秀的知识库。研究了浆料的流变学、可印刷性、路径厚度、方块电阻以及与基板的附着力。还对选定的层进行了扫描电子显微镜成像。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/4bafd264bcde/materials-16-01238-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/bc93f479749d/materials-16-01238-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/a80e8ad7894c/materials-16-01238-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/fe06cc1557e2/materials-16-01238-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/89e4e36870a2/materials-16-01238-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/4bafd264bcde/materials-16-01238-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/bc93f479749d/materials-16-01238-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/a80e8ad7894c/materials-16-01238-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/fe06cc1557e2/materials-16-01238-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/89e4e36870a2/materials-16-01238-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28b8/9921362/4bafd264bcde/materials-16-01238-g005.jpg

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本文引用的文献

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A New Frontier of Printed Electronics: Flexible Hybrid Electronics.印刷电子学的新前沿:柔性混合电子学。
Adv Mater. 2020 Apr;32(15):e1905279. doi: 10.1002/adma.201905279. Epub 2019 Nov 19.
2
Screen-Printing of a Highly Conductive Graphene Ink for Flexible Printed Electronics.用于柔性印刷电子的高导电性石墨烯油墨的丝网印刷
ACS Appl Mater Interfaces. 2019 Sep 4;11(35):32225-32234. doi: 10.1021/acsami.9b04589. Epub 2019 Aug 21.
3
Polymers for 3D Printing and Customized Additive Manufacturing.用于3D打印和定制增材制造的聚合物。
Chem Rev. 2017 Aug 9;117(15):10212-10290. doi: 10.1021/acs.chemrev.7b00074. Epub 2017 Jul 30.
4
Printed diodes operating at mobile phone frequencies.在手机频率下工作的印刷二极管。
Proc Natl Acad Sci U S A. 2014 Aug 19;111(33):11917-8. doi: 10.1073/pnas.1412312111. Epub 2014 Aug 6.
5
The fabrication, characterisation and electrochemical investigation of screen-printed graphene electrodes.丝网印刷石墨烯电极的制备、表征和电化学研究。
Phys Chem Chem Phys. 2014 Mar 14;16(10):4598-611. doi: 10.1039/c3cp55435j.
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Screen-printed biosensors in microbiology; a review.丝网印刷生物传感器在微生物学中的应用综述。
Talanta. 2010 Oct 15;82(5):1629-36. doi: 10.1016/j.talanta.2010.08.033. Epub 2010 Aug 27.