基于4-氨基-1,2,4-三唑的铁（II）自旋交叉纳米颗粒中两步自旋转变的观察
Observation of two-step spin transition in iron(II) 4-amino-1,2,4-triazole based spin crossover nanoparticles.
作者信息
Lalioti Nikolia, Giannopoulou Efstathia, Charitos Alexander, Parthenios John, Malina Ondrej, Polaskova Michaela, Kalarakis Alexandros, Tangoulis Vassilis
机构信息
Department of Chemistry, Laboratory of Inorganic Chemistry, University of Patras, 26504 Patras, Greece.
Institute of Chemical Engineering Sciences, Foundation of Research and Technology-Hellas (FORTH/ICE-HT), Stadiou Street, Platani, Patras, 26504 Greece.
出版信息
Dalton Trans. 2023 Mar 7;52(10):2937-2941. doi: 10.1039/d2dt04118a.
A synthetically controllable two-step spin transition was observed in iron(II) spin crossover nanoparticles of the dehydrated one-dimensional coordination polymer [Fe(NHtrz)]Br (NHtrz = 4-amino-1,2,4-triazole) using the reverse micellar method. The change from two-step to one-step hysteretic characteristics succeeded by changing the reaction time.
使用反胶束法，在脱水的一维配位聚合物[Fe(NHtrz)]Br（NHtrz = 4-氨基-1,2,4-三唑）的铁（II）自旋交叉纳米颗粒中观察到了一种可合成控制的两步自旋转变。通过改变反应时间，成功实现了从两步到一步滞后特性的转变。
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