Moon Jiyoung, Mehta Yash, Gundogdu Kenan, So Franky, Gu Qing
Electrical and Computer Engineering, The University of Texas at Dallas, Richardson, TX, 75080, USA.
Materials Science and Engineering, North Carolina State University, Raleigh, NC, 27695, USA.
Adv Mater. 2024 May;36(20):e2211284. doi: 10.1002/adma.202211284. Epub 2023 Jul 25.
Hybrid metal-halide perovskites (MHPs) have shown remarkable optoelectronic properties as well as facile and cost-effective processability. With the success of MHP solar cells and light-emitting diodes, MHPs have also exhibited great potential as gain media for on-chip lasers. However, to date, stable operation of optically pumped MHP lasers and electrically driven MHP lasers-an essential requirement for MHP laser's insertion into chip-scale photonic integrated circuits-is not yet demonstrated. The main obstacles include the instability of MHPs in the atmosphere, rudimentary MHP laser cavity patterning methods, and insufficient understanding of emission mechanisms in MHP materials and cavities. This review aims to provide a detailed overview of different strategies to improve the intrinsic properties of MHPs in the atmosphere and to establish an optimal MHP cavity patterning method. In addition, this review discusses different emission mechanisms in MHP materials and cavities and how to distinguish them.
混合金属卤化物钙钛矿(MHP)展现出了卓越的光电特性以及简便且经济高效的可加工性。随着MHP太阳能电池和发光二极管的成功,MHP作为片上激光器的增益介质也展现出了巨大潜力。然而,迄今为止,光泵浦MHP激光器和电驱动MHP激光器的稳定运行——这是MHP激光器融入芯片级光子集成电路的一项基本要求——尚未得到证实。主要障碍包括MHP在大气中的不稳定性、MHP激光腔图案化方法尚不完善,以及对MHP材料和腔体内发射机制的理解不足。本综述旨在详细概述不同策略,以改善MHP在大气中的固有特性,并建立一种优化的MHP腔图案化方法。此外,本综述还讨论了MHP材料和腔体内的不同发射机制以及如何区分它们。