Zhao Guanxiao, Fu Tao
Faculty of Mechanical and Electrical Engineering, Kunming University of Science and Technology, Kunming 650093, China.
Materials (Basel). 2023 Feb 22;16(5):1808. doi: 10.3390/ma16051808.
The shape memory polymer (SMP) is a new type of smart material that can produce a shape memory effect through the stimulation of the external environment. In this article, the viscoelastic constitutive theory of the shape memory polymer and the mechanism of the bidirectional memory effect of the shape memory polymer are described. A chiral poly cellular circular concave auxetic structure based on a shape memory polymer made of epoxy resin is designed. Two structural parameters, α and β, are defined, and the change rule of Poisson's ratio under different structural parameters is verified by ABAQUS. Then, two elastic scaffolds are designed to assist a new type of cellular structure made of a shape memory polymer to autonomously adjust bidirectional memory under the stimulation of the external temperature, and two processes of bidirectional memory are simulated using ABAQUS. Finally, when a shape memory polymer structure implements the bidirectional deformation programming process, a conclusion is drawn that changing the ratio β of oblique ligament and ring radius has a better effect than changing the angle α of oblique ligament and horizontal in achieving the autonomously adjustable bidirectional memory effect of the composite structure. In summary, through the combination of the new cell and the bidirectional deformation principle, the autonomous bidirectional deformation of the new cell is achieved. The research can be used in reconfigurable structures, tuning symmetry, and chirality. The adjusted Poisson's ratio achieved by the stimulation of the external environment can be used in active acoustic metamaterials, deployable devices, and biomedical devices. Meanwhile, this work provides a very meaningful reference for the potential application value of metamaterials.
形状记忆聚合物(SMP)是一种新型智能材料,能够通过外部环境刺激产生形状记忆效应。本文阐述了形状记忆聚合物的粘弹性本构理论以及形状记忆聚合物双向记忆效应的机理。设计了一种基于环氧树脂制成的形状记忆聚合物的手性多孔圆形凹形负泊松比结构。定义了两个结构参数α和β,并通过ABAQUS验证了不同结构参数下泊松比的变化规律。然后,设计了两种弹性支架,以辅助一种由形状记忆聚合物制成的新型细胞结构在外部温度刺激下自主调整双向记忆,并使用ABAQUS模拟了双向记忆的两个过程。最后,当形状记忆聚合物结构实现双向变形编程过程时,得出结论:在实现复合结构的自主可调双向记忆效应方面,改变斜韧带与环半径的比值β比改变斜韧带与水平方向的夹角α具有更好的效果。综上所述,通过新细胞与双向变形原理的结合,实现了新细胞的自主双向变形。该研究可应用于可重构结构、调谐对称性和手性。通过外部环境刺激实现的可调泊松比可应用于有源声学超材料、可展开装置和生物医学装置。同时,这项工作为超材料的潜在应用价值提供了非常有意义的参考。