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基于多主元合金化理论的材料设计与耐蚀性研究

Study on Material Design and Corrosion Resistance Based on Multi-Principal Component Alloying Theory.

作者信息

Ma Beiyi, Zhao Hongyang, Ju Dongying, Yang Zhibo, Chen Ming, Liu Qian

机构信息

School of Mechanical Engineering and Automation, University of Science and Technology Liaoning, Anshan 114051, China.

School of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan 114051, China.

出版信息

Materials (Basel). 2023 Feb 26;16(5):1939. doi: 10.3390/ma16051939.

Abstract

This study mainly attempts to develop Mg-based alloy materials with excellent corrosion resistance by means of multi-principal alloying. The alloy elements are determined based on the multi-principal alloy elements and the performance requirements of the components of biomaterials. MgZnSnSrBi alloy was successfully prepared by vacuum magnetic levitation melting. Through the electrochemical corrosion test with m-SBF solution (pH7.4) as the electrolyte, the corrosion rate of alloy MgZnSnSrBi alloy decreased to 20% of pure Mg. It could also be seen from the polarization curve that when the self-corrosion current density is low, the alloy shows superior corrosion resistance. Nevertheless, with the increase in self-corrosion current density, although the anodic corrosion performance of the alloy is obviously better than that of pure Mg, the cathode shows the opposite situation. The Nyquist diagram shows that the self-corrosion potential of the alloy is much higher than that of pure Mg. In general, under the condition of low self-corrosion current density, the alloy materials display excellent corrosion resistance. It is proved that the multi-principal alloying method is of positive significance for improving the corrosion resistance of Mg alloys.

摘要

本研究主要尝试通过多主元合金化的方式开发具有优异耐蚀性的镁基合金材料。基于多主元合金元素以及生物材料各组分的性能要求来确定合金元素。采用真空磁悬浮熔炼成功制备了MgZnSnSrBi合金。以m-SBF溶液(pH7.4)为电解液进行电化学腐蚀试验,合金MgZnSnSrBi合金的腐蚀速率降至纯镁的20%。从极化曲线也可以看出,当自腐蚀电流密度较低时,该合金表现出优异的耐蚀性。然而,随着自腐蚀电流密度的增加,尽管合金的阳极腐蚀性能明显优于纯镁,但阴极情况则相反。奈奎斯特图表明,该合金的自腐蚀电位远高于纯镁。总体而言,在自腐蚀电流密度较低的条件下,合金材料表现出优异的耐蚀性。证明了多主元合金化方法对于提高镁合金的耐蚀性具有积极意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3776/10004095/eed8af5f40cf/materials-16-01939-g001.jpg

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