Parmar Jayesh, Qureshi Asif
Department of Civil Engineering, Indian Institute of Technology (IIT) Hyderabad, Kandi, Sangareddy, TS 502285, India.
Department of Climate Change, Indian Institute of Technology (IIT) Hyderabad, Kandi, Sangareddy, TS 502285, India.
Environ Sci Technol. 2023 Mar 28;57(12):4763-4774. doi: 10.1021/acs.est.2c09438. Epub 2023 Mar 16.
Polychlorinated biphenyl compounds (PCBs) are highly toxic organic chemicals still prevalent in the environment. While global inventories of the use and emissions of PCBs have been developed, estimates for individual countries determined using bottom-up approaches are few and often show different trends from the global inventory. Here, we determine the past, present, and future consumption and emissions of PCBs in India. A mass balance model was used to estimate middle (low-high) emissions in the period 1950-2100. Up to 7296 tonnes of PCBs have been used in transformers. PCBs imported as wastes are estimated to be approximately 5000 (2400-9100) tonnes. Total emissions from the use and disposal of transformers, industrial processes, and imported waste disposal are estimated to become 13 (0.1-537) tonnes, 89.26 (0.5-178) tonnes, 63 (3-910) tonnes, respectively, in the period 1950-2100. Congener-specific emissions are relatively high for low-chlorinated PCBs (-8, 18, 28, 31, 52, 101, 110, 118, 153, range: 0.1-118 tonnes). We find that industrial emissions are becoming important sources of PCBs and may become predominant, depending on emission scenarios.
多氯联苯化合物(PCBs)是剧毒有机化学品,在环境中仍然普遍存在。虽然已经编制了多氯联苯使用和排放的全球清单,但采用自下而上方法确定的个别国家的估算数据很少,而且往往显示出与全球清单不同的趋势。在此,我们确定了印度多氯联苯过去、现在和未来的消费及排放情况。采用质量平衡模型估算了1950年至2100年期间的中等(低 - 高)排放量。变压器中已使用多达7296吨多氯联苯。估计作为废物进口的多氯联苯约为5000(2400 - 9100)吨。估计在1950年至2100年期间,变压器使用和处置、工业过程以及进口废物处置的总排放量分别为13(0.1 - 537)吨、89.26(0.5 - 178)吨、63(3 - 910)吨。低氯多氯联苯(-8、18、28、31、52、101、110、118、153,范围:0.1 - 118吨)的同类物特定排放量相对较高。我们发现,工业排放正成为多氯联苯的重要来源,并且根据排放情景可能会成为主要来源。