Calcined Clays from Nigeria-Properties and Performance of Supplementary Cementitious Materials Suitable for Producing Level 1 Concrete.

In this work, four naturally occurring (two kaolinite-rich and two smectite-rich) clay samples were collected from different areas around the Ashaka cement production plant, located in Gombe State, Nigeria and calcined in a laboratory. The mineralogical characterization of the clays was carried out by XRD. The hydration kinetics of the calcined clay-cement systems were monitored by isothermal calorimetry. Workability was determined using the flow table method. The reactivity of the calcined clays was determined from the solubility of Si and Al ions and the strength activity index. All calcined clays studied met the requirements of ASTM C618 for the use of natural pozzolans as a partial replacement for hydraulic cement. The metasmectite clays yielded a higher specific surface area, increased water demand, and less reactive Si and Al ions compared to the metakaolin clays. The two calcined clay groups require the addition of superplasticizer to achieve a workability class similar to the Portland cement mortar system. They can be used to replace Portland cement at replacement levels of up to 45%, in combination with limestone powder to form an LC cement, thereby achieving at least a "Level 1" reduction in greenhouse gas emissions.