Zhen Zhen, Qu Chuan, Fu Donghui
BAIMTEC Material Co., Ltd., Beijing 100094, China.
Department of Mechanics, Tianjin University, Tianjin 300350, China.
Materials (Basel). 2023 Apr 6;16(7):2910. doi: 10.3390/ma16072910.
Electron beam physical vapour deposition (EB-PVD) technology is a standard industrial method for the preparation of a thermal barrier coating (TBC) deposition on aeroengines. The internal stress of EB-PVD TBCs, including stress inside the top coating (TC) and thermal oxidation stress during long-term service is one of the key reasons for thermal barrier failures. However, research on the synergistic characterization of the internal stress of EB-PVD TBCs is still lacking. In this work, the stress inside the TC layer and the thermal oxidation stress of EB-PVD TBC during long-term thermal cycles were synergistically detected, combining Cr-PLPS and THz-TDS technologies. Based on a self-built THz-TDS system, stress-THz coefficients and of the EB-PVD TBC, which are the core parameters for stress characterization, were calibrated for the first time. According to experimental results, the evolution law of the internal stress of the TC layer was similar to that of the TGO stress, which were interrelated and influenced by each other. In addition, the internal stress of the TC layer was less than that of the TGO stress due to the columnar crystal microstructure of EB-PVD TBCs.
电子束物理气相沉积(EB-PVD)技术是在航空发动机上制备热障涂层(TBC)的一种标准工业方法。EB-PVD热障涂层的内应力,包括顶层涂层(TC)内部的应力以及长期服役期间的热氧化应力,是热障失效的关键原因之一。然而,目前仍缺乏对EB-PVD热障涂层内应力协同表征的研究。在这项工作中,结合Cr-PLPS和太赫兹时域光谱(THz-TDS)技术,对TC层内部的应力以及EB-PVD热障涂层在长期热循环过程中的热氧化应力进行了协同检测。基于自行搭建的太赫兹时域光谱系统,首次标定了EB-PVD热障涂层的应力-太赫兹系数 和 ,这是应力表征的核心参数。根据实验结果,TC层内应力的演变规律与热生长氧化物(TGO)应力的演变规律相似,二者相互关联、相互影响。此外,由于EB-PVD热障涂层的柱状晶微观结构,TC层的内应力小于TGO应力。