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电极化掺锂 ZnO 纳米棒修饰纳米纤维空气滤器的过滤效率和抗菌性能的协同增强

Synergistic Enhancement of Filtering Efficiency and Antibacterial Performance of a Nanofiber Air Filter Decorated with Electropolarized Lithium-Doped ZnO Nanorods.

机构信息

Department of Electrical Engineering, Chungnam National University, Daejeon 34134, Korea.

College of Pharmacy, Yeungnam University, Gyeongsan 38541, Korea.

出版信息

ACS Appl Mater Interfaces. 2023 May 3;15(17):20977-20986. doi: 10.1021/acsami.3c00744. Epub 2023 Apr 18.

Abstract

According to clinical case reports, bacterial co-infection with COVID-19 can significantly increase mortality, with () being one of the most common pathogens causing complications such as pneumonia. Thus, during the pandemic, research on imparting air filters with antibacterial properties was actively initiated, and several antibacterial agents were investigated. However, air filters with inorganic nanostructures on organic nanofibers (NFs) have not been investigated extensively. This study aimed to demonstrate the efficiency of electropolarized poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) NFs decorated with Li-doped ZnO nanorods (NRs) to improve the filtering ability and antibacterial activity of the ultrathin air filter. The surfactant was loaded onto the ZnO─known for its biocompatibility and low toxicity─nanoparticles (NPs) and transferred to the outer surface of the NFs, where Li-doped ZnO NRs were grown. The Li-doped ZnO NR-decorated NF effectively enhanced the physical filtration efficiency and antibacterial properties. Additionally, by exploiting the ferroelectric properties of Li-doped ZnO NRs and PVDF-TrFE NFs, the filter was electropolarized to increase its Coulombic interaction with PMs and . As a result, the filter exhibited a 90% PM removal efficiency and a 99.5% sterilization rate against . The method proposed in this study provides an effective route for simultaneously improving the air filter performance and antibacterial activity.

摘要

根据临床病例报告,COVID-19 的细菌合并感染可显著增加死亡率,其中()是导致肺炎等并发症的最常见病原体之一。因此,在大流行期间,积极开展了赋予空气过滤器抗菌特性的研究,并研究了几种抗菌剂。然而,带有有机纳米纤维(NFs)上的无机纳米结构的空气过滤器尚未得到广泛研究。本研究旨在展示用掺锂氧化锌纳米棒(NRs)修饰的电极化聚(偏二氟乙烯-三氟乙烯)(PVDF-TrFE)NFs 提高超薄空气过滤器的过滤能力和抗菌活性的效率。将表面活性剂负载到 ZnO 上-以其生物相容性和低毒性而闻名-纳米颗粒(NPs)并转移到 NF 的外表面,在那里生长掺锂氧化锌 NRs。掺锂氧化锌 NR 修饰的 NF 有效地提高了物理过滤效率和抗菌性能。此外,通过利用掺锂 ZnO NR 和 PVDF-TrFE NFs 的铁电特性,对过滤器进行了极化,以增加其与 PM 和的库仑相互作用。结果,该过滤器对 PM 的去除效率达到 90%,对的杀菌率达到 99.5%。本研究提出的方法为同时提高空气过滤器性能和抗菌活性提供了一条有效途径。

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