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球磨处理对水中污染物生物炭吸附效果的影响:一项荟萃分析。

Effects of ball milling on biochar adsorption of contaminants in water: A meta-analysis.

机构信息

State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China; University of Chinese Academy of Sciences, Beijing 100049, China.

State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China; Institute of Environment Pollution Control and Treatment, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China.

出版信息

Sci Total Environ. 2023 Jul 15;882:163643. doi: 10.1016/j.scitotenv.2023.163643. Epub 2023 Apr 20.

Abstract

Reckless release of contaminants into the environment causes pollution in various aquatic systems on a global scale. Biochar is potentially an inexpensive and environmentally friendly adsorbent for removing contaminants from water. Ball milling has been used to enhance biochar's functionality; however, global analysis of the effect of ball milling on biochar's capacity to adsorb contaminants in aqueous solutions has not yet been done. Here, we conducted a meta-analysis to investigate the effects of ball milling on the adsorption/removal capacity of biochar for contaminants in aqueous solutions, and to investigate whether ball milling effects are related to biochar production, ball milling, and other experimental variables. Overall, ball milling significantly increased biochar adsorption capacity towards both inorganic and organic contaminants, by 69.9% and 561.9%, respectively. This could be attributed to ball milling increasing biochar surface area by 2.05-fold, pore volume by 2.39-fold, and decreasing biochar pH by 0.83-fold. The positive adsorption effects induced by ball milling varied widely, with the most effective being ball milling for 12 to 24 h at 300 to 400 rpm with a biochar:ball mass ratio of 1:100 on biochars produced at 400-550 °C from wood residues. Based on this meta-analysis, we conclude that ball milling could effectively enhance biochar's ability to remove organic and inorganic contaminants from aquatic systems.

摘要

将污染物任意排放到环境中会导致全球范围内各种水生系统的污染。生物炭作为一种潜在的廉价且环保的吸附剂,可用于去除水中的污染物。球磨已被用于增强生物炭的功能;然而,全球范围内尚未对球磨对生物炭在水溶液中吸附污染物能力的影响进行分析。在这里,我们进行了一项荟萃分析,以研究球磨对生物炭吸附水溶液中污染物能力的影响,并研究球磨效果是否与生物炭生产、球磨和其他实验变量有关。总体而言,球磨显著提高了生物炭对无机和有机污染物的吸附能力,分别提高了 69.9%和 561.9%。这可能归因于球磨将生物炭的表面积增加了 2.05 倍,孔体积增加了 2.39 倍,pH 值降低了 0.83 倍。球磨引起的吸附效果呈显著差异,最有效的是在 300-400 rpm 下球磨 12-24 小时,生物炭与球的质量比为 1:100,生物炭是由 400-550°C 下的木屑制成。基于这项荟萃分析,我们得出结论,球磨可以有效地提高生物炭从水生系统中去除有机和无机污染物的能力。

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