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甲壳素作为含氮生物质的催化转化。

Catalytic conversion of chitin as a nitrogen-containing biomass.

机构信息

Komaba Institute for Science, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan.

Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan.

出版信息

Chem Commun (Camb). 2023 May 23;59(42):6301-6313. doi: 10.1039/d3cc00902e.

Abstract

The conversion of chitin enables the utilisation of naturally-fixed nitrogen in addition to carbon toward establishing a sustainable carbon and nitrogen cycle. Chitin is an abundant biomass, 100 Gt per year, but most chitin-containing waste is discarded due to its recalcitrant properties. This feature article summarises the challenges and our work on chitin conversion to -acetylglucosamine and oligomers with fascinating applications. Afterwards, we introduce recent progress on the chemical transformation of -acetylglucosamine, followed by a discussion of future perspectives based on current status and findings.

摘要

甲壳素的转化使我们能够利用自然固定的氮和碳来建立可持续的碳氮循环。甲壳素是一种丰富的生物质,每年有 100 亿吨,但由于其顽固的特性,大多数含甲壳素的废物都被丢弃了。本文总结了甲壳素转化为 -乙酰氨基葡萄糖和低聚物的挑战和我们的工作,这些低聚物具有迷人的应用。之后,我们介绍了 -乙酰氨基葡萄糖化学转化的最新进展,并根据目前的现状和发现讨论了未来的展望。

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