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利用真空蒸馏技术实现废油基钻井液的实际场地回收利用。

Achieving Practical Venue Recycle of Waste Oil-Based Drilling Fluids with Vacuum Distillation Technology.

作者信息

Ma Shukui, Zhang Guilei, Shi Chenghui, Dong Qiyu, Ji Teng

机构信息

China Oilfield Services Limited, Tian Jin 300459, China.

出版信息

ACS Omega. 2023 Apr 26;8(18):16306-16314. doi: 10.1021/acsomega.3c00967. eCollection 2023 May 9.

Abstract

Drilling fluids are essential operating additives for extracting oil and shale gas. Thus, their pollution control and recycling utilization are significant to petrochemical development. Vacuum distillation technology was used in this research to handle waste oil-based drilling fluids and achieve reutilization. Briefly, recycled oil and recovered solids can be obtained from waste oil-based drilling fluids whose density is 1.24-1.37 g/cm by vacuum distillation under the condition of an external heat transfer oil temperature of 270 ± 5 °C and a reaction pressure below 5 × 10 Pa. Meanwhile, recycled oil has excellent apparent viscosity (AV, 21 mPa·s) and plastic viscosity (PV, 14 mPa·s), which could be used as a substitute for 3# white oil. Furthermore, PF-ECOSEAL prepared by recycled solids exhibited better rheological properties (27.5 mPa·s AV, 18.5 mPa·s PV, and 9 Pa yield point) and plugging performance (32 mL , 1.90 mL/min) than drilling fluids prepared with the conventional plugging agent PF-LPF. Our work confirmed that vacuum distillation is a valid technology in innocuity treatment and resource utilization of drilling fluids and has great value in industrial applications.

摘要

钻井液是石油和页岩气开采过程中必不可少的作业添加剂。因此,其污染控制和循环利用对石化行业的发展具有重要意义。本研究采用真空蒸馏技术处理废油基钻井液并实现其再利用。简而言之,在外部传热油温为270±5℃、反应压力低于5×10 Pa的条件下,通过真空蒸馏可从密度为1.24 - 1.37 g/cm的废油基钻井液中获得回收油和回收固体。同时,回收油具有优异的表观粘度(AV,21 mPa·s)和塑性粘度(PV,14 mPa·s),可替代3#白油。此外,由回收固体配制的PF - ECOSEAL表现出比用传统堵漏剂PF - LPF配制的钻井液更好的流变性能(AV为27.5 mPa·s,PV为18.5 mPa·s,屈服点为9 Pa)和堵漏性能(32 mL,1.90 mL/min)。我们的工作证实,真空蒸馏是一种有效的钻井液无害化处理和资源利用技术,在工业应用中具有很大价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5df/10173441/badff416fa68/ao3c00967_0002.jpg

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