基于 BODIPY 的一维共价有机框架用于光催化有氧氧化。
A BODIPY-Based 1D Covalent Organic Framework for Photocatalytic Aerobic Oxidation.
机构信息
Lanzhou Petrochemical Research Center, Petrochemical Research Institute, PetroChina, 1 Heshui North Road, Xigu District, Lanzhou, 730060, China.
College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, 601 West Huangpu Avenue, Tianhe District, Guangzhou 510632, China.
出版信息
Chem Asian J. 2023 Jul 3;18(13):e202300328. doi: 10.1002/asia.202300328. Epub 2023 May 31.
Covalent organic frameworks (COFs) as metal-free photocatalysts have attracted extensive interest. However, the organic transformations photocatalyzed by COFs under mild conditions remain a challenge. Herein, a boron-dipyrromethene (BODIPY) based 1D COF, namely JNM-12, was facilely constructed by Schiff-base condensation reaction. JNM-12 exhibited strong visible-light harvesting abilities and suitable photocatalysis energy potentials, enabling the activation of O to superoxide anions (O ⋅ ) and singlet oxygen ( O ) under visible light irradiation. Benefiting from these properties, JNM-12 delivered excellent photocatalytic activity in the O ⋅ -mediated oxidative coupling of amines and O -engaged aerobic oxidation of enamines. Our work paves a new way for synthesis of COFs as efficient, economical, and green photocatalysts for organic synthesis.
共价有机框架（COFs）作为无金属光催化剂引起了广泛关注。然而，在温和条件下 COFs 催化的有机转化仍然是一个挑战。在此，通过席夫碱缩合反应简便地构建了一种基于硼二吡咯甲烷（BODIPY）的 1D COF，即 JNM-12。JNM-12 表现出较强的可见光吸收能力和适宜的光催化能量势，可在可见光照射下将 O 激活为超氧阴离子（O ⋅ ）和单线态氧（ O ）。得益于这些特性，JNM-12 在 O ⋅ 介导的胺的氧化偶联和 O 参与的烯胺的有氧氧化反应中表现出优异的光催化活性。我们的工作为合成 COFs 作为高效、经济和绿色的有机合成光催化剂开辟了新途径。
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