College of Bioresources and Materials Engineering, Shaanxi University of Science & Technology, Xi'an, Shaanxi, 710021, PR China; Department of Chemistry and Environmental Engineering, Hubei Minzu University, Enshi 445000, Hubei, PR China.
College of Bioresources and Materials Engineering, Shaanxi University of Science & Technology, Xi'an, Shaanxi, 710021, PR China.
Ecotoxicol Environ Saf. 2023 Jul 1;259:115053. doi: 10.1016/j.ecoenv.2023.115053. Epub 2023 May 23.
The development of nuclear energy has led to the depletion of uranium resources and now presents the challenge of treating radioactive wastewater. Extracting uranium from seawater and nuclear wastewater has been identified as an effective strategy for addressing these issues. However, extracting uranium from nuclear wastewater and seawater is still extremely challenging. In this study, an amidoxime-modified feather keratin aerogel (FK-AO aerogel) was prepared using feather keratin for efficient uranium adsorption. The FK-AO aerogel showed an impressive adsorption capacity of 585.88 mg·g in an 8 ppm uranium solution, with a calculated maximum adsorption capacity of 990.10 mg·g. Notably, the FK-AO aerogel demonstrated excellent selectivity for U(VI) in simulated seawater that contained coexisting heavy metal ions. In a uranium solution having a salinity of 35 g·L and a concentration of 0.1-2 ppm, the FK-AO aerogel achieved a uranium removal rate of greater than 90 %, indicating its effectiveness in adsorbing uranium in environments having high salinity and low concentration. This suggests that FK-AO aerogel is an ideal adsorbent for extracting uranium from seawater and nuclear wastewater, and it is also expected that it could be used in industrial applications for extracting uranium from seawater.
核能的发展导致了铀资源的枯竭,现在又面临着处理放射性废水的挑战。从海水中和核废水中提取铀已被确定为解决这些问题的有效策略。然而,从核废水中和海水中提取铀仍然极具挑战性。在这项研究中,采用羽毛角蛋白制备了一种偕胺肟改性羽毛角蛋白气凝胶(FK-AO 气凝胶),用于高效吸附铀。FK-AO 气凝胶在 8 ppm 的铀溶液中表现出令人印象深刻的吸附容量 585.88 mg·g-1,计算出的最大吸附容量为 990.10 mg·g-1。值得注意的是,FK-AO 气凝胶在含有共存重金属离子的模拟海水中对 U(VI)表现出优异的选择性。在盐度为 35 g·L 和浓度为 0.1-2 ppm 的铀溶液中,FK-AO 气凝胶的铀去除率大于 90%,表明其在高盐度和低浓度环境中吸附铀的有效性。这表明 FK-AO 气凝胶是一种从海水和核废水中提取铀的理想吸附剂,有望在从海水中提取铀的工业应用中得到应用。