Institute of Solid-State Physics, Graz University of Technology, Graz 8010, Austria.
Department of Engineering, FT Technologies (UK) Ltd., Sunbury-on-Thames TW16 7DX, United Kingdom.
ACS Appl Mater Interfaces. 2023 Jun 7;15(22):27206-27213. doi: 10.1021/acsami.3c03840. Epub 2023 May 26.
Controlling water transport and management is crucial for continuous and reliable system operation in harsh weather conditions. Passive strategies based on nonwetting surfaces are desirable, but so far, the implementation of superhydrophobic coatings into real-world applications has been limited by durability issues and, in some cases, lack of compliance with environmental regulations. Inspired by surface patterning observed on living organisms, in this study we have developed durable surfaces based on contrast wettability for capillary-driven water transport and management. The surface fabrication process combines a hydrophobic coating with hard-anodized aluminum patterning, using a scalable femtosecond laser microtexturing technique. The concept targets heavy-duty engineering applications; particularly in aggressive weather conditions where corrosion is prevalent and typically the anodic aluminum oxide-based coating is used to protect the surface from corrosion, the concept has been validated on anodic aluminum oxide coated aluminum alloy substrates. Such substrates with contrast wettable characteristics show long-term durability in both natural and lab-based artificial UV and corrosion tests where superhydrophobic coatings tend to degrade.
控制水传输和管理对于在恶劣天气条件下实现连续可靠的系统运行至关重要。基于不润湿表面的被动策略是理想的,但迄今为止,将超疏水涂层应用于实际应用一直受到耐久性问题的限制,在某些情况下,还不符合环境法规。受生物表面图案的启发,本研究开发了基于对比润湿性的耐用表面,用于毛细驱动的水传输和管理。该表面制造过程结合了疏油涂层和硬质阳极氧化铝图案化,使用可扩展的飞秒激光微加工技术。该概念针对重型工程应用;特别是在腐蚀性强的恶劣天气条件下,通常使用基于阳极氧化铝的涂层来保护表面免受腐蚀,该概念已经在涂有阳极氧化铝的铝合金基板上得到验证。具有对比润湿性的此类基板在自然和基于实验室的人工 UV 和腐蚀测试中具有长期耐久性,而超疏水涂层往往会在此类测试中降解。