Zhang Yufeng, Li Chunyan, Lou Ziwei, Zhang Penghe, Zhang Yan, Shen Shuangyuan, Ruan Guanjie, Zhang Jiaying
College of Mathematics and Physics, Shanghai University of Electric Power, Shanghai 201306, China.
Shanghai Key Laboratory of High Temperature Superconductors, Shanghai University, Shanghai 200444, China.
Micromachines (Basel). 2023 Apr 30;14(5):987. doi: 10.3390/mi14050987.
The multiseeding technique is a method to grow large-sized REBaCuO (REBCO, where is a rare earth element) high temperature superconducting bulks. However, due to the existence of grain boundaries between seed crystals, the superconducting properties of bulks are not always better than those of single grain bulks. In order to improve the superconducting properties caused by grain boundaries, we introduced buffer layers with a diameter of 6 mm in the growth of GdBCO bulks. Using the modified top-seeded melt texture growth method (TSMG), that is, YBaCuO (Y123) as the liquid phase source, two GdBCO superconducting bulks with buffer layers with a diameter of 25 mm and a thickness of 12 mm were successfully prepared. The seed crystal arrangement of two GdBCO bulks with a distance of 12 mm were (100/100) and (110/110), respectively. The trapped field of the GdBCO superconductor bulks exhibited two peaks. The maximum peaks of superconductor bulk S (100/100) were 0.30 T and 0.23 T, and the maximum peaks of superconductor bulk S (110/110) were 0.35 T and 0.29 T. The critical transition temperature remained between 94 K and 96 K, with superior superconducting properties. The maximum of S appeared in specimen b5, which was 4.5 × 10 A/cm. Compared with S, the value of S had obvious advantages in a low magnetic field, medium magnetic field and high magnetic field. The maximum value appeared in specimen b2, which was 4.65 × 10 A/cm. At the same time, it showed an obvious second peak effect, which was attributed to Gd/Ba substitution. Liquid phase source Y123 increased the concentration of the Gd solute dissolved from Gd211 particles, reduced the size of Gd211 particles and optimized . For S and S under the joint action of the buffer and the Y123 liquid source, except for the contribution of Gd211 particles to be the magnetic flux pinning center with the improvement of , the pores also played a positive role in improving the local . More residual melts and impurity phases were observed in S than in S, which had a negative impact on the superconducting properties. Thus, S exhibited a better trapped field and .
多籽晶技术是一种生长大尺寸稀土钡铜氧化物(REBCO,其中RE为稀土元素)高温超导块材的方法。然而,由于籽晶之间存在晶界,块材的超导性能并不总是优于单晶晶粒块材。为了改善由晶界引起的超导性能,我们在生长钆钡铜氧(GdBCO)块材时引入了直径为6毫米的缓冲层。采用改进的顶部籽晶熔融织构生长法(TSMG),即以钇钡铜氧(Y123)作为液相源,成功制备了两块直径为25毫米、厚度为12毫米且带有缓冲层的GdBCO超导块材。两块间距为12毫米的GdBCO块材的籽晶排列分别为(100/100)和(110/110)。GdBCO超导块材的俘获场呈现出两个峰值。超导块材S(100/100)的最大峰值分别为0.30特斯拉和0.23特斯拉,超导块材S(110/110)的最大峰值分别为0.35特斯拉和0.29特斯拉。临界转变温度保持在94开尔文至96开尔文之间,具有优异的超导性能。S的最大Jc出现在样品b5中,为4.5×10⁴安/平方厘米。与S相比,S的Jc值在低磁场、中磁场和高磁场下具有明显优势。最大Jc值出现在样品b2中,为4.65×10⁴安/平方厘米。同时,它表现出明显的第二峰值效应,这归因于钆/钡替代。液相源Y123提高了从Gd211颗粒溶解的钆溶质的浓度,减小了Gd211颗粒的尺寸并优化了Jc。对于在缓冲层和Y123液相源共同作用下的S和S,除了Gd211颗粒随着Jc的提高成为磁通钉扎中心的贡献外,孔隙在改善局部Jc方面也起到了积极作用。在S中观察到比S更多的残余熔体和杂质相,这对超导性能有负面影响。因此,S表现出更好的俘获场和Jc。