Zhao Baocai, Fu Jianye, Zhou Chuanli, Yu Liangmin, Qiu Meng
College of Chemistry and Chemical Engineering, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao, 266100, China.
College of Chemistry and Chemical Engineering, China University of Petroleum, Qingdao, 266555, China.
Small. 2023 Sep;19(39):e2301917. doi: 10.1002/smll.202301917. Epub 2023 Jun 1.
Two-Dimensional (2D) materials have attracted immense attention in recent years. These materials have found their applications in various fields, such as catalysis, adsorption, energy storage, and sensing, as they exhibit excellent physical, chemical, electronic, photonic, and biological properties. Recently, researchers have focused on constructing porous structures on 2D materials. Various strategies, such as chemical etching and template-based methods, for the development of surface pores are reported, and the porous 2D materials fabricated over the years are used to develop supercapacitors and energy storage devices. Moreover, the lattice structure of the 2D materials can be modulated during the construction of porous structures to develop 2D materials that can be used in various fields such as lattice defects in 2D nanomaterials for enhancing biomedical performances. This review focuses on the recently developed chemical etching, solvent thermal synthesis, microwave combustion, and template methods that are used to fabricate porous 2D materials. The application prospects of the porous 2D materials are summarized. Finally, the key scientific challenges associated with developing porous 2D materials are presented to provide a platform for developing porous 2D materials.
近年来,二维(2D)材料引起了极大关注。这些材料因其具有优异的物理、化学、电子、光子和生物学特性,已在催化、吸附、能量存储和传感等各个领域得到应用。最近,研究人员专注于在二维材料上构建多孔结构。报道了各种用于开发表面孔隙的策略,如化学蚀刻和基于模板的方法,多年来制备的多孔二维材料被用于开发超级电容器和能量存储装置。此外,在构建多孔结构的过程中,可以对二维材料的晶格结构进行调制,以开发可用于二维纳米材料晶格缺陷等各个领域以增强生物医学性能的二维材料。本综述重点关注最近开发的用于制备多孔二维材料的化学蚀刻、溶剂热合成、微波燃烧和模板法。总结了多孔二维材料的应用前景。最后,提出了与开发多孔二维材料相关的关键科学挑战,以为开发多孔二维材料提供一个平台。