Enhancing electrocatalytic methanol oxidation of Pd-Ir nanoalloy through electron-rich catalytic interface induced by incorporating phosphorus.

Incorporating less expensive nonmetal phosphorus (P) into noble metal-based catalysts has become a developing strategy to enhance the catalytic performance of electrocatalysts for methanol electrooxidation reaction (MOR), attributing to the electronic and synergistic structure alteration mechanism. In the work, three-dimensional nitrogen-doped graphene anchoring ternary Pd-Ir-P nanoalloy catalyst (PdIrP/NG) was prepared by co-reduction strategy. As a multi-electron system, elemental P adjusts the outer electron structure of Pd and diminishes the particle size of nanocomposites, which heightens the electrocatalytic activity effectively and accelerate MOR kinetics in alkaline medium. The study reveals that the electron effect and ligand effect induced by P atoms on the hydrophilic and electron-rich surface of PdIr/NG and PdIrP/NG samples can reduce the initial oxidation potential and peak potential of CO, showing significantly enhanced the anti-poisoning ability compared with commercial Pd/C as the benchmark. Meanwhile, the stability of PdIrP/NG is significantly higher than that of commercial Pd/C. The facile synthetic approach provides an economic option and a new vision for the development of electrocatalysts in MOR.