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具有出色太阳能/电热性能的多功能磁性海绵,用于高效全天连续清理原油泄漏。

Multifunctional magnetic sponge with outstanding solar/electro-thermal performance for high-efficiency and all-day continuous cleanup of crude oil spills.

作者信息

Yang Xiao, Wang Bo, Ma Shuai, Qi Jiahuan, Chen Zhenfeng, Feng Yuezhan, Liu Chuntai, Shen Changyu

机构信息

College of Materials Science and Engineering, National Engineering Research Center for Advanced Polymer Processing Technology, Key Laboratory of Materials Processing and Mold of Ministry of Education, Zhengzhou University, Zhengzhou, Henan 450001, China.

College of Materials Science and Engineering, National Engineering Research Center for Advanced Polymer Processing Technology, Key Laboratory of Materials Processing and Mold of Ministry of Education, Zhengzhou University, Zhengzhou, Henan 450001, China.

出版信息

Sci Total Environ. 2023 Sep 20;892:164601. doi: 10.1016/j.scitotenv.2023.164601. Epub 2023 Jun 2.

Abstract

The high-efficient, eco-friendly and low-energy cleanup of viscous crude oil spills is still a global challenge. Emerging absorbents with self-heating function are promising candidates due to that they can significantly decrease crude oil viscosity via in-situ heat transfer so as to accelerate remediation. Herein we developed a novel multifunctional magnetic sponge (P-MXene/FeO@MS) with outstanding solar/electro-thermal performance by facilely coating TiCT MXene, nano-FeO and polydimethylsiloxane onto melamine sponge for fast crude oil recovery. Superior hydrophobicity (water contact angle of 147°) and magnetic responsivity allowed P-MXene/FeO@MS to be magnetically driven for oil/water separation and easy recycling. Owing to excellent full-solar-spectrum absorption (average absorptivity of 96.5 %), effective photothermal conversion and high conductivity (resistance of 300 Ω), P-MXene/FeO@MS possessed remarkable solar/Joule heating capability. The maximum surface temperature of P-MXene/FeO@MS could quickly reach 84 °C under a solar irradiation of 1.0 kW/m and 100 °C after applying a voltage of 20 V. The generated heat induced a significant decrease of crude oil viscosity, enabling the composite sponge to absorb more than 27 times its weight of crude oil within 2 min (1.0 kW/m irradiation). More importantly, by means of the synergistic effect of Joule heating and solar heating, a pump-assisted absorption device based on P-MXene/FeO@MS was able to realize the high-efficiency and all-day continuous separation of high-viscosity oil on water surface (crude oil flux = 710 kg m h). The new-typed multifunctional sponge provides a competitive approach for dealing with large-area crude oil pollution.

摘要

高效、环保且低能耗地清理粘性原油泄漏仍是一项全球性挑战。具有自热功能的新型吸附剂是很有前景的候选材料,因为它们可以通过原位热传递显著降低原油粘度,从而加速修复过程。在此,我们通过将TiCT MXene、纳米FeO和聚二甲基硅氧烷轻松涂覆在三聚氰胺海绵上,开发了一种具有出色太阳能/电热性能的新型多功能磁性海绵(P-MXene/FeO@MS),用于快速回收原油。优异的疏水性(水接触角为147°)和磁响应性使P-MXene/FeO@MS能够通过磁力驱动实现油/水分离并易于回收利用。由于具有出色的全光谱吸收能力(平均吸收率为96.5%)、有效的光热转换和高电导率(电阻为300Ω),P-MXene/FeO@MS具有显著的太阳能/焦耳加热能力。在1.0kW/m的太阳辐射下,P-MXene/FeO@MS的最高表面温度可迅速达到84°C,施加20V电压后可达100°C。产生的热量使原油粘度显著降低,使复合海绵在2分钟内(1.0kW/m辐射)能够吸收超过其自身重量27倍的原油。更重要的是,通过焦耳加热和太阳能加热的协同作用,基于P-MXene/FeO@MS的泵辅助吸收装置能够实现水面上高粘度油的高效全天连续分离(原油通量 = 710kg m h)。这种新型多功能海绵为处理大面积原油污染提供了一种有竞争力的方法。

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