Fine aerosol sources at an urban background site in the Eastern Mediterranean (Nicosia; Cyprus): Insights from offline versus online source apportionment comparison for carbonaceous aerosols.

A total of 348 daily PM samples were collected at an urban background site of Nicosia, capital of Cyprus, for one-year period (October 2018-October 2019) to assess the origin and sources of fine PM at the Eastern Mediterranean, a poorly characterized area of the world. The samples were analysed for water soluble ionic species, elemental and organic carbon, carbohydrates and trace metals, the combination of which were utilized to identify pollution sources by applying Positive Matrix Factorization (PMF). Six PM sources, namely long-range transport (LRT; 38 %), traffic (20 %), biomass burning (16 %), dust (10 %), sea salt (9 %) and heavy oil combustion (7 %), were identified. Despite sampling in an urban agglomeration, the chemical fingerprint of the aerosol is largely dictated by air mass origin rather than local sources. Springtime is characterized by the most elevated particulate levels due to the southerly air masses carrying particles from the Sahara Desert. Northerlies are observed throughout the year but are predominant during summer allowing the LRT source to peak (54 % during summer). Only during winter, due to extensive use of biomass combustion for domestic heating (36.6 % during winter), local sources dominate. A co-located online PMF source apportionment of submicron carbonaceous aerosols (Organic Aerosols, OA; Black Carbon) was performed by the means of an Aerosol Chemical Speciation Monitor (for OA) and an Aethalometer (for BC) for a four-month period. The comparison between the two methodologies allowed to better assess the robustness and limitations of the two methodologies. More specifically, LRT OA and biomass burning BC apportioned by the offline PMF showed a strong consistency with the online apportioned more oxidized oxygenated OA and BC, respectively; cross validating these sources. On the other hand, our traffic factor may contain additional hydrocarbon-like OA and BC from fossil fuel sources other than just vehicular emissions. Finally, the offline biomass burning OA source is likely to contain both primary and secondary OA.