Mohar Mrittika, Ghosh Sumit, Hajra Alakananda
Department of Chemistry, Visva-Bharati (A Central University), Santiniketan, 731235, India.
Chem Rec. 2023 Nov;23(11):e202300121. doi: 10.1002/tcr.202300121. Epub 2023 Jun 12.
Harnessing visible-light in organic synthesis is one of the most effective methods that aligns with green and sustainable chemistry principles and hence skyrocketed in the last two decades. Similarly, three-component 1,2-dicarbofunctionalization of alkenes and alkynes has recently been a great choice to construct complex molecular systems in an easy and rapid manner. Therefore, light-induced reactions can be an excellent alternative to carry out 1,2-dicarbofunctionalization reactions, and very recently, organic chemists across the globe have fascinated us with their interesting articles. In this present review, we have summarized the recent advancements in the area of visible light induced three-component 1,2-dicarbofunctionalization of alkenes and alkynes till March 2023. We have categorized the discussion based on the catalysts used to carry out the transformations for better understanding and different important aspects of these transformations have also been covered.
在有机合成中利用可见光是符合绿色和可持续化学原则的最有效方法之一,因此在过去二十年中得到了迅速发展。同样,烯烃和炔烃的三组分1,2-二碳官能化最近成为以简便快速的方式构建复杂分子体系的绝佳选择。因此,光诱导反应可以成为进行1,2-二碳官能化反应的极佳替代方法,最近,全球的有机化学家们发表的有趣文章让我们着迷。在本综述中,我们总结了截至2023年3月在可见光诱导的烯烃和炔烃三组分1,2-二碳官能化领域的最新进展。我们根据用于进行转化的催化剂对讨论进行了分类,以便更好地理解,并且还涵盖了这些转化的不同重要方面。