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一种新型纳米颗粒耦合膨胀颗粒堵漏剂的合成与性能评价

Synthesis and Performance Evaluation of a Novel Nanoparticle Coupling Expanded Granule Plugging Agent.

作者信息

Li Xuejiao, Li Qi, Fu Meilong, Li Li, Su Lingyang, Wang Yingyang

机构信息

Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, China.

College of Petroleum Engineering, Yangtze University, Wuhan 430100, China.

出版信息

Gels. 2023 Jun 12;9(6):479. doi: 10.3390/gels9060479.

Abstract

This study focuses on the characteristics of fractured and vuggy high-temperature and high-salt reservoirs in the Tahe Oilfield. The Acrylamide/2-acrylamide-2-methylpropanesulfonic copolymer salt was selected as a polymer; the hydroquinone and hexamethylene tetramine was selected as the crosslinking agent with a ratio of 1:1; the nanoparticle SiO was selected, and its dosage was optimized to 0.3%; Additionally, a novel nanoparticle coupling polymer gel was independently synthesized. The surface of the gel was a three-dimensional network structure, with grids arranged in pieces and interlaced with each other, and the structure was very stable. The SiO nanoparticles were attached to the gel skeleton, forming effective coupling and enhancing the strength of the gel skeleton. To solve the problem of complex gel preparation and transportation, the novel gel is compressed, pelletized, and dried into expanded particles through industrial granulation, and the disadvantage of the rapid expansion of expanded particles is optimized through physical film coating treatment. Finally, a novel nanoparticle coupling expanded granule plugging agent was developed. Evaluation of the performance of the novel nanoparticle coupling expanded granule plugging agent. With an increase in temperature and mineralization, the expansion multiplier of granules decreases; aged under high-temperature and high-salt conditions for 30 days, the expansion multiplier of granules can still reach 3.5 times, the toughness index is 1.61, and the long-term stability of the granules can be good; the water plugging rate of granules is 97.84%, which is superior to other widely used particle-based plugging agents.

摘要

本研究聚焦于塔河油田裂缝性和孔洞性高温高盐油藏的特征。选用丙烯酰胺/2-丙烯酰胺-2-甲基丙磺酸盐共聚物作为聚合物;选用对苯二酚和六亚甲基四胺作为交联剂,比例为1:1;选用纳米二氧化硅(SiO),并将其用量优化至0.3%;此外,自主合成了一种新型纳米颗粒耦合聚合物凝胶。凝胶表面为三维网络结构,网格呈片状排列且相互交错,结构非常稳定。SiO纳米颗粒附着在凝胶骨架上,形成有效耦合,增强了凝胶骨架的强度。为解决凝胶制备和运输复杂的问题,通过工业造粒将新型凝胶压缩、造粒并干燥成膨胀颗粒,并通过物理覆膜处理优化膨胀颗粒快速膨胀的缺点。最终,研制出一种新型纳米颗粒耦合膨胀颗粒堵漏剂。对新型纳米颗粒耦合膨胀颗粒堵漏剂的性能进行评价。随着温度和矿化度的升高,颗粒的膨胀倍数降低;在高温高盐条件下老化30天,颗粒的膨胀倍数仍可达到3.5倍,韧性指数为1.61,颗粒的长期稳定性良好;颗粒的堵水率为97.84%,优于其他广泛使用的颗粒类堵漏剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cee/10298431/a35fdb3c6b11/gels-09-00479-g001.jpg

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