Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui 230026, China.
CAS Key Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.
J Chem Phys. 2023 Jul 14;159(2). doi: 10.1063/5.0155585.
In this paper, we present an extended dissipaton equation of motion for studying the dynamics of electronic impurity systems. Compared with the original theoretical formalism, the quadratic couplings are introduced into the Hamiltonian accounting for the interaction between the impurity and its surrounding environment. By exploiting the quadratic fermionic dissipaton algebra, the proposed extended dissipaton equation of motion offers a powerful tool for studying the dynamical behaviors of electronic impurity systems, particularly in situations where nonequilibrium and strongly correlated effects play significant roles. Numerical demonstrations are carried out to investigate the temperature dependence of the Kondo resonance in the Kondo impurity model.
本文提出了一个扩展的耗散运动方程,用于研究电子杂质系统的动力学。与原始理论形式相比,二次耦合被引入到哈密顿量中,以描述杂质与其周围环境的相互作用。通过利用二次费米子耗散代数,所提出的扩展耗散运动方程为研究电子杂质系统的动力学行为提供了一个有力的工具,特别是在非平衡和强关联效应起重要作用的情况下。数值演示被用来研究 Kondo 杂质模型中 Kondo 共振的温度依赖性。