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巴基斯坦卡纽瓦尔地区地下水和生物样本中的砷含量

Arsenic level in groundwater and biological samples in Khanewal, Pakistan.

作者信息

Khan Najeeb Ullah, Shahid Muhammad, Khalid Sana, Natasha Natasha, Alothman Zeid A, Al-Kahtani Abdullah A, Imran Muhammad, Murtaza Behzad

机构信息

Department of Environmental Sciences, COMSATS University Islamabad, Vehari Campus, Vehari, 61100, Pakistan.

Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia.

出版信息

Environ Geochem Health. 2023 Dec;45(12):8943-8952. doi: 10.1007/s10653-023-01682-w. Epub 2023 Jul 13.

Abstract

Groundwater is the most valuable natural source in our earth's planet, being contaminated in various regions worldwide. Despite considerable research, there are scarce data regarding arsenic (As) levels in groundwater and its build-up in biological samples in Pakistan. The current investigation analyzed As contamination in four tehsils of District Khanewal (Kabirwala tehsil, Jahaniyan tehsil, Mian Channu tehsil, and Khanewal tehsil). For that, 123 groundwater samples, 19 animal milk samples, 20 human nails, and 20 human hair samples were collected from the study area. Arsenic concentration in groundwater was up to 51.8 µg/L with an average value of 7.2 µg/L. About 28 water samples (23%) had As contents > WHO limit and 38 samples (31%) > DEP-NJ limit. Low levels of As were detected in biological samples. Average As levels were 23 µg/L in the milk samples and 298 µg/kg in human hair. Arsenic contents were not detected in nail samples, except in one sample from Kabirwala tehsil. The maximum values of hazard quotient and cancer risk in District Khanewal were 4.9 and 0.0022, respectively. It is anticipated that long-term use of As-containing water may led to poisoning of humans in the study area, especially in Kabirwala. Therefore, it is necessary to monitor As contamination in the groundwater of Kabirwala tehsil to reduce the potential health hazards.

摘要

地下水是地球上最宝贵的自然资源,但在全球各个地区都受到了污染。尽管进行了大量研究,但关于巴基斯坦地下水砷(As)含量及其在生物样本中的积累情况的数据却很稀少。本次调查分析了卡内瓦尔县四个乡(卡比尔瓦拉乡、贾哈尼扬乡、米安詹努乡和卡内瓦尔乡)的砷污染情况。为此,从研究区域采集了123份地下水样本、19份动物奶样本、20份人类指甲样本和20份人类头发样本。地下水中的砷浓度高达51.8微克/升,平均值为7.2微克/升。约28份水样(23%)的砷含量超过了世界卫生组织的限值,38份水样(31%)超过了新泽西州环境保护部的限值。在生物样本中检测到的砷含量较低。奶样本中的平均砷含量为23微克/升,人类头发中的平均砷含量为298微克/千克。除了卡比尔瓦拉乡的一个指甲样本外,在其他指甲样本中均未检测到砷含量。卡内瓦尔县的危害商数和癌症风险的最大值分别为4.9和0.0022。预计长期使用含砷水可能会导致研究区域的人类中毒,尤其是在卡比尔瓦拉地区。因此,有必要监测卡比尔瓦拉乡地下水中的砷污染情况,以减少潜在的健康危害。

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